NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics

NCERT Solutions for Class 12 Chemistry Chapter 4 provides excellent solutions for the questions asked in the textbook. The step wise solutions and diagrammatic representations make the concepts easy to understand. The subject experts have given the best explanations to the queries. The students appearing for the board exams or competitive exams can refer to these for better preparations.

CBSE, MP board, UP board, Gujarat board, etc. have the NCERT Solutions for reference in the curriculum. Chemistry is an important subject and requires conceptual analysis. The detailed explanations in the NCERT Solutions for Class 12 Chemistry Chapter 4 will help the students to score well in the examination.

Board CBSE
Textbook NCERT
Class Class 12
Subject Chemistry
Chapter Chapter 4
Chapter Name Chemical Kinetics
Number of Questions Solved 39
Category NCERT Solutions

NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics

Class 12 Chemistry chapter 4 Chemical Kinetics is an important chapter and is often asked in the examination. Chemical kinetics helps to understand the chemical reactions. This chapter explains all about the rate of reaction and the factors determining the rate of reaction.

NCERT IN-TEXT QUESTIONS

Question 1.
For a reaction R → P, the concentration of a reactant changes from 0·03 M to 0·02 M in 25 minutes. Calculate the average rate of the reaction using the units of seconds.
Answer:
For a reaction, R → P
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 1

Question 2.
In a reaction, 2A → Products, the concentration of A decreases from 0·5 mol L-1 to 0·4 mol L-1 in 10 minute. Calculate the rate during this interval.
Answer:
For the reaction: 2A → Products
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 2

Question 4.
Fora reaction,A+B —> Product; the rate law is given by, r =k [ A]1/2 [B]2. What is the order of the reaction?
Answer:
Order of reaction. = 1/2+ 2 = 21/2 or 2.5

Question 4.
The conversion of the molecules X to Y follows second order kinetics. If concentration of X is increased to three times, how will it affect the rate of formation of Y ?
Answer:
For the reaction X → Y
Reaction rate (r) = k[X]2
If the concentration be increased to three times, then
Reaction rate (r’) = k [3X]2
\(\frac { { r }^{ ‘ } }{ r } =\frac { k\left[ 3X \right] ^{ 2 } }{ k\left[ X \right] ^{ 2 } } =9\)

Question 5.
A first order reaction has rate constant of 1·15 x 10-3 s-1. How long will 5 g of this reactant take to reduce to 3g?
Answer:
For the first order reaction,
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 3

Question 6.
Time required to decompose SO2Cl2 to half of its initial concentration is 60 minutes. If the decomposition is a first order reaction, calculate the rate constant of the reaction.
Answer:
For the first order reaction ;
Rate constant (k) = \(\frac { 0.693 }{ { t }_{ 1/2 } } =\frac { 0.693 }{ \left( 60min \right) } \)
= \(\frac { 0.693 }{ \left( 60\times 60s \right) } =1.925\times { 10 }^{ -4 }{ s }^{ -1 }\)

Question 7.
What will be the effect of temperature on rate constant?
Answer:
With the rise in temperature by 10°, the rate constant of a reaction is nearly doubled. The dependence of rate constant on temperature is given the Arrhenius equation, k = A e-Ea/RT where A is the Arrhenius constant and Ea is activation energy of the reaction.

Question 8.
In general, it is observed that the rate of a chemical reaction doubles with every 10° rise in temperature. If the generalisation holds for a reaction in the temperature range 295 K to 305 K, what would be the value of activation energy for the reaction? (C.B.S.E. Delhi2005 Supp., Pb. Board2007)
Answer:
According to Arrhenius equation,
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 4

Question 9.
The activation energy for the reaction, 2HI(g) → H2(g) + I2(g) is 208·5 kJ mol-1. Calculate fraction of molecules of reactants having energy equal to or greater than activation energy.
Answer:
The fraction of the molecules (x) having energy equal to or more than activation energy may be calculated as follows :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 5

NCERT Exercise

Question 1.
The rate expression for the following reactions determine the order of reaction and the dimensions of the rate constant.
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 6
Answer:
(a) 2
(b) 2
(c) 3/2
(d) 1

Question 2.
For the reaction, 2A + B → A2 B, the rate = k [AJ[B]2 with k = 2.0 x 10-6 mol-2 L2 s-1. Calculate the initial rate of the reaction when [A] = 0.1 mol L-1, [B] = 0.2 mol L-1. Calculate the rate of reaction after [A] is reduced to 0.06 mol L-1.
Answer:
Initial rate of reaction = k [A] [B]2
= (20 x 10-6 mol-2 s-1) (0.1 mol L-1) (0.2 mol L-1)2 = 8 x 10-9molL-1 s-1.
When [A] is reduced from 010 mol L-1 to 0.06 molL-1, i.e., 0.04 mol L-1 of A has reacted, the concentration of B reacted, is = 1/2 x 0.04 mol L-1 = 0.02 mol L-1
Concentration of B, remained after reaction with A = 0.2 – 0-02=0.18 mol L-1
Now, rate=(20 x 10-6 mol-2 L2 s-1) (0.06 mol L-1) (0.18 molL-1)2
= 3-89 x 10-9mol L-1 s-1

Question 3.
The rate of decomposition of NH3 on the platinum surface is zero order. What is the rate of production of N2 and H2 if k = 2·5 x 10-4 Ms-1? (C.B.S.E. Delhi 2008)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 7

Question 4.
The decomposition of dimethyl ether leads to the formation of CH4, H2, and CO, and the reaction rate is given by the expression:
rate = k [CH3OCH3]3/2
The rate of reaction is followed by increase in pressure in a close vessel and the rate can also be expressed in terms of partial pressure of dimethyl ether :
rate = k [pCH3OCH3]3/2
If the pressure is measured in bar and time in minutes, then what are the units of rate and rate constant ?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 8

Question 5.
Mention the factors that affect the rate of a chemical reaction.
Answer:

  • Concentration of reactants
  • Temperature
  • Nature of reactants and products
  • Exposure to light (Radiation)
  • Presence of catalysts.

Question 6.
A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is
(i) doubled
(ii) reduced to 1/2? (C.B.S.E. Outside Delhi 2008, 2009)
Answer:
Let the reaction be; A → Products
Reaction rate (r) = k [A]2 (for second order reaction)
(i) When concentration is doubled, the rate of reaction may be expressed as :
Reaction rate (r’) = k [2A]2
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 9
reaction rate becomes four times.
(ii) When concentration is reduced to half, the rate of reaction may be expressed as :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 10
reaction rate will be reduced to 1/4.

Question 7.
What is the effect of temperature on the rate constant of a reaction? How can this effect of temperature on rate constant be represented quantitatively?
Answer:
Increasing the temperature on decreasing the activation energy will result in an increase in the rate of reaction and an exponential increase in the rate constant. On increasing the temperature the fraction of molecules which collide with energy greater than Ea increases and hence the rate constant (exponentially)
K = A -ea/RT, quantitative representation of temperature effect on rate constant.

Question 8.
In pseudo-first-order hydrolysis of ester in water, the following results were obtained.
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 11
(i) Calculate the average rate of reaction between the time interval 30 to 60 seconds.
(ii) Calculate the pseudo first order rate constant for the hydrolysis of ester.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 12

Question 9.
A reaction is first order in A and second order in B
(i) Write differential rate equation.
(ii) How is rate affected when the concentration of B is tripled?
(iii) How is rate affected when the concentration of both A and B are doubled? (C.B.S.E. Outside Delhi 2010, 2013)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 13

Question 10.
In a reaction between A and B, the initial rate of reaction was measured for different initial concentration of A and B as given ahead :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 14
What is the order of reaction with respect to A and B?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 15

Question 11.
The following data were obtained at 300 K for the reaction 2A + B → C + D:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 16
Calculate the rate of formation of D when [A] = 0·5 mol L-1 and [B] = 0·2 mol L-1.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 17
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 18

Question 12.
The reaction between A and B is first order with respect to A and zero-order with respect to B. Fill in the blanks in the following table:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 19
Answer:
The rate equation for the reaction is: r = k [A]1 [B]0
(i) Comparing experiments I and II,
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 20
Thus, the concentration of A in experiment II is 0·2 M
(ii) Comparing experiments II and in.
When the concentration of A is made double, the reaction rate will also become twice.
∴ Rate of reaction in experiment III is 8·0 x 10-2
(iii) Comparing experiments I and IV.
Since the reaction rates are the same in both the experiments, the molar concentration of A in experiment IV must be the same as in experiment I i. e., it must be 0·1 M.

Question 13.
Calculate the half-life of the first-order reaction from their rate constants given as
(a) 200 s-1
(b) 2 min-1
(c) 4 year-1.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 21

Question 14.
The half-life for the radioactive decay of 14C is 5730 Y. An archaeological artifact contained wood had only 80% of the 14 C found in a living tree. Estimate the age of the sample. (C.B.S.E. Delhi 2008)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 22
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 23

Question 15.
The experimental data for decomposition of N2O2 [2N2O5 → 4NO2 + O2] in gas phase at 318 K are given below :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 24
(a) Plot [N2O5] against t
(b) Find the half-life period for the reaction
(c) Draw a graph between log [N2O5] and t
(d) What is rate law?
(e) Calculate the rate constant
(f) Calculate the half-life period from k and compare it with (b).
Answer:
The available data is:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 25
(b) Initial cone. of N2O5 = 1·63 x 10-2M. Half of initial cone. = 1/2 x (1·63 x 10-2 M) = 0·815 x 10-2 M Time corresponding to half of inital concentration (t/2) from the plot (a) = 1400 (s) approximately
(c) The graph of log [N2O5] Vs. time has been plotted.
(d) Since the graph between log [N2O5] and time is a straight line the reaction is of the first order
The rate equation : rate (r) = k[N2O5]
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 26
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 27

Question 16.
The rate constant for the first-order reaction is 60 s-1. How much time will it take to reduce the initial concentration of the reactant to its 1/16th value? (C.B.S.E. Delhi 2013)
Answer:
For the first-order reaction
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 28

Question 17.
During a nuclear explosion, one of the products is 90Sr with a half period of 28·1 Y. If 1 pg of 90Sr was absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60 years if it is not lost metabolically?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 29
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 30

Question 18.
For a first-order reaction, show that the time required for 99% completion is twice the time required for the completion of 90% of the reaction.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics image - 4
Question 19.
A first-order reaction takes 40 minutes for 30% decomposition. Calculate its half-life period. (C. B. S. E. Outside Delhi 2013)
Answer:
tiwari academy class 12 chemistry Chapter 4 Chemical Kinetics 40

Question 20.
For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data is obtained.
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 38
Calculate the rate constant.
Answer:
The decomposition reaction is of gaseous nature and the expression of the rate equation for the reaction is :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 39

Question 21.
The following data were obtained during the first-order thermal decomposition of SO2Cl2 at a constant volume.
SO2Cl2 (g) → SO2 (g) + Cl2(g)
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 41
Calculate the rate of the reaction when the total pressure is 0·65 atm. (C.B.S.E. Sample Paper 2011)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 42
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 43

Question 22.
The rate constant for the decomposition of N2O5 at various temperatures is given below :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 44
Draw a graph between ln k and 1/T and calculate the values of A and Ea. Predict the rate constant at 30° and 50°C.
Answer:
To draw the plot of log K versus 1/T, we can re-write the given data as follows :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 45
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 46
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 47

Question 23.
The rate constant for the decomposition of a hydrocarbon is 2.418 × 10-5 s-1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of the pre-exponential factor.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics image - 5
Question 24.
Consider a certain reaction A → Products with k = 2·0 x 10-2 s-1. Calculate the concentration of A remaining after 100 s if the initial concentration of A is 1·0 mol L-1.
Answer:
For the first-order reaction :
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 48

Question 25.
Sucrose decomposes in acid solution into glucose and fructose according to the first-order rate law with t1/2 = 3·0 hrs. What fraction of the sample of sucrose remains after 8 hours? (C.B.S.E. Sample Paper 2011)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 49

Question 26.
The decomposition of a hydrocarbon follows the equation :
k = (4·5 x 1011 s-1)e-28000k/T.
Calculate the energy of activation (Ea).
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 50

Question 27.
The rate constant for the first-order decomposition of H2O2 is given by the following equation:
log k = 14·34 – 1·25 x 104K/T.
Calculate the Ea for the reaction. At what temperature will the half-life period be 256 minutes?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 51

Question 28.
The decomposition of A into the product has a value of k as 4·5 x 103 s-1 at 10°C and energy of activation 60 kJ mol-1. At what temperature would k be 1·5 x 104 s-1? (C.B.S.E. Sample Paper 2011)
Answer:
According to Arrhenius equation,
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 52

Question 29.
The time required for 10% completion of a first-order reaction at 298 K is equal to that required for its 25% completion at 308 K. If the value of A is 4 x 1010s-1, calculate k at 318 K and Ea.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 53
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 54

Question 30.
The rate of a particular reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the energy of activation of the reaction (R = 8·314 JK-1 mol-1). (C.B.S.E. Outside Delhi 2013)
Answer:
According to Arrhenius equation,
NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics 55

We hope the NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics help you. If you have any query regarding NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 History Chapter 8 Peasants, Zamindars and the State Agrarian Society and the Mughal Empire

NCERT Solutions for Class 12 History Chapter 8 Peasants, Zamindars and the State Agrarian Society and the Mughal Empire are part of NCERT Solutions for Class 12 History. Here we have given NCERT Solutions for Class 12 History Chapter 8 Peasants, Zamindars and the State Agrarian Society and the Mughal Empire.

Board CBSE
Textbook NCERT
Class Class 12
Subject History
Chapter Chapter 8
Chapter Name Peasants, Zamindars and the State Agrarian Society and the Mughal Empire
Number of Questions Solved 9
Category NCERT Solutions

NCERT Solutions for Class 12 History Chapter 8 Peasants, Zamindars and the State Agrarian Society and the Mughal Empire

Question l.
What are the problems in using the Ain as a source for reconstructing agrarian history ? How do historians deal with this situation ?
Solution :
(a) Problems : The Ain was revised five times by the author so that it might become authentic. In all the quantitative sections, all numeric data were reproduced in words so as to minimise the chances of errors. But in spite this there are following problems in using Ain as a source for reconstructing agrarian history :

  1. Numerous errors in totalling have been detected. These are ascribed to simple slips of arithmetic or of transcription by Abul Fazl’s assistants.
  2. Another problem is about the somewhat skewed nature of the quantitative data. Data were not collected uniformly from all provinces. For example, detailed information about caste composition of the zamindars was collected from many subas. However, such information is not available for Bengal and Orissa.
  3. Prices and wages that have been documented in the Ain pertains to areas in or around the imperial capital of Agra. It has, therefore, limited relevance for the rest of the country.
  4. Ain was to present a vision of Akbar’s empire where social harmony was provided by a strong ruling class. There was no place for a successful revolt against the Mughal state. Thus, whatever we learn about the peasants from the Ain remains a view from the top.

(b)

  1. The historians deal with the above problems by supplementing the descriptions contained in sources emanating from regions away from the Mughal capital, e.g., revenue records from Gujarat, Maharashtra and Rajasthan from the seventeenth and eighteenth centuries.
  2. The extensive records of the East India Company too provide useful descriptions of agrarian relations in eastern India. These sources describe the instances of conflicts between peasants, zamindars and the state. Thus, they provide an insight into peasants’ perception of and their expectations of fairness from the state.

Question 2.
To what extent is it possible to characterise agricultural production in the sixteenth- seventeeth centuries as subsistence agriculture? Give reasons for your answer.
Solution :
(a) During Mughal, India was basically an agricultural country. In the Mughal state of India a different varieties of crops were produced. In Bengal two varieties of rices were produced. But the focus on the cultivation of basic crops does not mean that only subsistence agriculture existed in medieval India.
(b) The Mughal state encouraged peasants to cultivate varieties of crops which brought in revenue especially cotton and sugarcane.
(c) Cotton was mainly grown in vast area which was spread over central India and the deccan plateau, whereas in Bengal sugarcane was mainly produced.
(d) Many varieties of cash crops such as oilseeds including mustard and lentils.
(e) An average peasant of that time grew both commercial and subsistence crops.

Question 3.
Describe the role played by women in agricultural production.
Solution :
The role played by women in agricultural production was as mentioned below :

  • Men and women worked shoulder to shoulder in the fields.
  • Men tilled and ploughed, while women sowed, weeded, threshed and winnowed the harvest.
  • During the medieval period, with the growth of nucleated villages and expansion in individuated peasant farming, the basis of production was the labour and resources of the entire household.
  • Inspite of above, there were biases related to women’s biological functions. For example, menstruating women were not allowed to touch the plough or the potter’s wheel in western India, or enter the groves where betel-leaves (paan) were grown in Bengal.

Question 4.
Discuss, with examples, the significance of monetary transactions during the period under consideration.
Solution :
The significance of monetary transactions during the period (sixteenth and seventeenth centimes) was substantial because the Mughal Empire was among the greatest empires that had managed to consolidate its power and resources. There was stability in the Ming (China), Safavid (Iran) and Ottoman (Turkey) empires. This stability led to create vibrant networks of overland trade from China to the Mediterranean Sea. The discovery of New World resulted in massive expansion of trade of India with Europe.

With the expansion of trade the importance of monetary transactions increased. The expansion of trade brought huge amount of bullion and silver into India where there was no natural resource of silver. This led to remarkable stability in the availability of metal currency, particularly in silver rupya in India. This facilitated an unprecedented expansion of minting of coins and the circulation of money in the economy. At the same time, there was no exchange of goods or barter system during this period. The payments were made in gold or silver coins. According to Giovanni Careri, all the gold and silver which circulates throughout the world, ultimately, comes into India due to its overseas trade. Thus a large amounts of cash transactions took place in the sixteenth and seventeenth centuries.

Question 5.
Examine the evidence that suggests that land revenue was important for the Mughal fiscal system.

Solution :
(i) Agriculture was the mainstay of the economy. Land Revenue collected was used to pay salaries and to meet different kinds of administrative expenses. So it was considered important to establish an administrative apparatus to ensure control over agricultural production.

(ii) Thus, before fixing land revenue, Mughal state first acquired specific information about the extent of agricultural lands and their produce.

(iii) Land revenue collection arrangements was consisted of two stages of assessment. These were Jama and hasil. Cultivators were given the choice to pay land revenue either in cash or kind. The state preferred to collect land revenue as cash. Attempts were made to maximize profits from the land revenue collection.

(iv) Both cultivated and cultivable lands were measured in each province to fix land revenue. According to a decree of Akbar, it was the responsibility of malguzar to make cultivator pay land revenue in kind and it was also kept open. Thus, it is clear from the evidence that the monetary transactions were very important. To continue this policy efforts by subsequent emperors like Aurangzeb continued to measure land for collection of land revenue.

Question 6.
To what extent do you think caste was a factor in influencing social and economic relations in agrarian society ?
Solution :
Agricultural production involved the intensive participation and initiative of the peasantry. There were different social groups, on the basis of caste and other factors, that were involved in agricultural expansion. This affected their social and economic relations in the agrarian society in the following ways :

  1. Deep inequalities on the basis of caste and other caste like distinctions made the cultivators a highly heterogeneous group.
  2. Among those who tilled the land, there was a sizeable number who worked as menials or agricultural labourers (majur).
  3. There was abundance of cultivable land but inspite of this certain caste groups were assigned menial tasks and were relegated to poverty. Such groups comprised a large section of the village population. They had the least resources and were constrained by their position in the caste hierarchy like the Dalits of modem India.
  4. In Muslim communites too menials like halalkhoran (scavengers) were housed outside the boundaries of the village. The mallahzadas (sons of boatmen) in Bihar were comparable to slaves.

Thus, there was a direct correlation between caste, poverty and social status at the lower level of society. It was, however, not so at the intermediate levels. For example, in Marwar, Rajputs were considered peasants like Jats who were accorded a lower status in the caste hierarchy. The Gauravas, who cultivated land around Vrindavan sought Rajput status in the seventeenth century. Ahirs, Gujars and Malis rose in the hierarchy due to the profitability of cattle rearing and horticulture.

Question 7.
How were the lives of forest dwellers transformed in the sixteenth and seventeenth centuries ?
Solution :
The forest dwellers were people who earned their livelihood by gathering of forest produce, hunting and shifting agriculture. These activities changed according to seasons. For example, the Bhils collected forest produce in the spring. They did fishing in the summer, cultivated during the monsoon months. They did hunting in the winter and autumn. Such a division of activities presumed and perpetuated mobility which was a distinctive feature of the forest dwellers. However, their lives were transformed in the sixteenth and seventeenth centuries in the following ways :

  1. In the sixteenth and seventeenth centuries, the state required elephants for the army. So, the peshkash – a form of tribute collected by the Mughal state – in the form of elephants too.
  2. In the Mughal political ideology, the hunt symbolised the overwhelming concern of the state to ensure justice to all the subjects, rich and poor. Thus, during hunting expeditions, the emperor personally attended to the grievances of the people. Such hunting expeditions affected the lives of the forest dwellers.
  3. Forests were cleaned for agricultural settlements. The spread of commercial agriculture impinged on the lives of forest dwellers, who lived on forest products like honey, beeswax and gum lac. Gum lac was exported from India. Elephants were captured and sold. There was [ exchange of commodities through barter too. All this changed due to commercial agriculture and agricultural settelments.
  4. Social factors too transformed the lives of forest dwellers. For example, chieftains of many tribes had become zamindars, some even became kings. They built up their armies and demanded that their fraternity to provide military service. In Assam, the Ahom kings had their paiks. They were people who obliged to render military service in exchange for land. Not only this the capture of wild elephants was declared a royal monopoly by the Ahom kings.
  5. With the establishment of tribal kingdoms in the north-east, war became a common feature.
  6. The cultural influences as that of sufi saints encouraged the forest-dwellers particularly agricultural communities to accept Islam.

Question 8.
Examine the role played by zamindars in Mughal India.
Solution :
Zamindars played a significant role in Mughal India as mentioned below :

  1. The zamindars had landed properties and enjoyed certain social and economic privileges due to their superior status in the society and due performance of certain services (khidmat) for the state.
  2. They had milkiyat lands which were cultivated for the private use of zamindars with the help of hired or servile labour. The zamindars could sell, bequeath or mortgage these lands at will.
  3. The zamindars collected revenue on behalf of the state. They were compensated for this financially.
  4. They had military resources such as armed contingent and fortresses (qilachas).
  5. In the social hierarchy, the zamindars constituted its very narrow apex.
  6. Contemporary documents give an impression that conquest may have been source of the origin of some zamindaris. A powerful military chieftain often dispossessed weaker people and expanded his zamindari.
  7. Zamindars spearheaded the colonisation of agricultural land. They helped in settling cultivators by providing them with the means of cultivation, including cash loans. The buying and selling of zamindaris accelerated the process of monetisation in the countryside. Zamindars sold the produce from their milkiyat lands and established markets (haats) where peasants came to sell their produce too.
  8. Although the zamindars were considered as an exploitative class but their relationship with the peasants were based on reciprocity, paternalism and patronage because the bhakti saints did not portray them as exploiters or oppressors of peasantry. Not only this, in a large ‘ number of agrarian uprisings in north India in the seventeenth century, zamindars often received the support of the peasantry in their struggle against the state.

Question 9.
Discuss the ways in which panchayats and village headmen regulated rural , society.
Solution :
Panchayats and village headmen regulated the rural society in the following ways :

  1. The village panchayat was an assembly of elders. Its decisions were binding on the members.
  2. The panchayat was headed by a headman known as muqaddam or mandal. The headman supervised the preparation of accounts, assisted by the accountant or patwari of the panchayat.
  3. The panchayat ensured that the caste boundaries among the various communities inhabitating the village were upheld. In eastern India all marriages were held in the presence of the mandal or headman. Thus, the headman was to oversee the conduct of the members of the village community “chiefly to prevent any offence against their caste”.
  4. Panchayats had the authority to levy fines and inflict serious punishments such as expulsion from the community. Such punishment was given as a deterrant to violation of caste norms.
  5. There were Jati panchayats of each caste. In Rajasthan, Jati panchayats arbitrated civil disputes between members of different castes. They decided the disputes related to claims on lands and marriages. Generally, the state respected the decisions of Jati panchayats.
  6. Sometimes petitions were presented to the panchayat complaining about extortionate taxation or the demand for unpaid labour (begar) imposed by the “superior” castes or officials of the state. These were submitted by the lower classes because they regarded the village panchayat as the court of appeal that would ensure that the state carried out its moral obligations and guaranteed justice. In such cases, the panchayats often suggested compromise and reconciliation. In case of failure of compromise, the peasants generally deserted the village because there was abundance of uncultivated land available in the villages.

We hope the NCERT Solutions for Class 12 History Chapter 8 Peasants, Zamindars and the State Agrarian Society and the Mughal Empire help you. If you have any query regarding NCERT Solutions for Class 12 History Chapter 8 Peasants, Zamindars and the State Agrarian Society and the Mughal Empire, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 Physics Chapter 12 Atoms

NCERT Solutions for Class 12 Physics Chapter 12 Atoms

NCERT Solutions for Class 12 Physics Chapter 12 Atoms are part of NCERT Solutions for Class 12 Physics. Here we have given. NCERT Solutions for Class 12 Physics Chapter 12 Atoms.

Board CBSE
Textbook NCERT
Class Class 12
Subject Physics
Chapter Chapter 12
Chapter Name Atoms
Number of Questions Solved 17
Category NCERT Solutions

Question 1.
Choose the correct alternative from clues given at end of each statement:

  1. The size of the atom in Thomson’s model is the atomic size in Rutherford’s model.(much greater than/no different from/much less than.)
  2. In the ground state of…………… electrons are in stable equilibrium, while in ……………..  electrons always experience a net force. (Thomson’s model/Rutherford’s model.)
  3. A classical atom based on…………. is doomed to collapse. (Thomson’s model/Rutherford’s model.)
  4. An atom has a nearly continuous mass distribution in a………….. but has a highly non­uniform mass distribution in (Thomson’s model/Rutherford’s model.)
  5. The positively charged part of the atom possesses most of the mass in…………. (Rutherford’s model/both the models.)

Answer:

  1. no different from
  2. Thomson’s model; Rutherford’s model.
  3. Rutherford’s model.
  4. Thomson’s model, Rutherford’s model.
  5. both the models.

Question 2.
Suppose you are given a chance to repeat the alpha-particle scattering experiment using a thin sheet of solid hydrogen in place of the gold foil. (Hydrogen is a solid at a temperature 14 K). What results do you expect?
Answer:
The nucleus of a hydrogen atom is a proton. The mass of it is 1.67 x 10-27 kg, whereas the mass of an incident α-particle is 6.64 x 10-27 kg. Because the scattering particle is more massive than the target nuclei (proton). the α-particle won’t bounce back in even in a head-on collision. It is similar to a football colliding with a tennis ball at rest. Thus, there would be no large-angle scattering.

Question 3.
What is the shortest wavelength present in the Paschen series of spectral lines?
Answer:
The wavelength of the spectral lines forming the Paschen series is given by

NCERT Solutions for Class 12 Physics Chapter 12 Atoms 1
Question 4.

A difference of 2.3 eV separates two energy levels in an atom. What is the frequency of radiation emitted when the atom transits from the upper level to the lower level?
Answer:
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 2
Question 5.
The ground state energy of the hydrogen atom is -13.6 eV. What are the kinetic and potential energies of the electron in this state?
Answer:
K.E. = -E (Total energy)
= -(-13.6) = 13.6 eV
P.E. = 2 X E = 2 X (-13.6)
= -27.2 eV

Question 6.
A hydrogen atom initially in the ground level absorbs a photon which excites it to the n = 4 level. Determine the wavelength and frequency of the photon.
Answer:
We know, the energy of an electron in the nth orbit of a hydrogen atom is given by
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 3
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 4

Question 7.
(a) Using Bohr’s model, calculate the speed of the electron in a hydrogen atom in the n = 1, 2, and 3 levels.
(b) Calculate the orbital period in each of these levels.
Answer:
(a) Speed of an electron in nth orbit of a hydrogen atom is given by
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 5

NCERT Solutions for Class 12 Physics Chapter 12 Atoms 6

Question 8.
The radius of the innermost electron orbit of a hydrogen atom is 5.3 x 10-11 m. What are the radii of the n = 2 and n = 3 orbits?
Answer:
We know, the radius of the nth orbit of a hydrogen atom is given by rn = r0n2, where r0 = 5.3 x 10-u m is the radius of the innermost orbit of the hydrogen atom.
When n = 2, r2 = 5.3 x 10-u x 4
= 2.12 x 10-10m
When n = 3,
= 5.3 x 10-11 x 9
= 4.77 x 10-10m.

Question 9.
A 12.75 eV electron beam is used to bombard gaseous hydrogen at room temperature. What series of wavelengths will be emitted?
Answer:

NCERT Solutions for Class 12 Physics Chapter 12 Atoms 7
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 8

Question 10.
In accordance with Bohr’s model, And the quantum number that characterizes the earth’s revolution around the sun in an orbit of radius 1.5 x 1011 m with an orbital speed
3 x 1014 m s-1. (Mass of earth = 6.0 x 1024 kg.)
Answer:
According to Bohr’s postulate of quantization of angular momentum
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 9

Question 11.
Answer the following questions, which help you understand the difference between Thomson’s model and Rutherford’s model better.
(a) Is the average angle of deflection of a-particles by a thin gold foil predicted by Thomson’s model much less, about the same, or much greater than that predicted by Rutherford’s model?
(b) Is the probability of backward scattering (i.e., scattering of a-particles at angles greater than 90°) predicted by Thomson’s model much less, about the same, or much greater than that predicted by Rutherford’s model?
(c) Keeping other factors fixed, it is found experimentally that for small thickness t, the number of a-particles scattered at moderate angles is proportional to What clue does this linear independence on t provide?
(d) In which model is it completely wrong to ignore multiple scattering for the calculation of the average angle of scattering of a-particles by a thin foil?
Answer:
(a) About the same
(b) Much less
(c) It suggests that the scattering is predominantly due to a single collision, because the chance of a single collision increases linearly with the number of target atoms, and hence linearly with thickness.
(d) In Thomson’s model, a single collision causes very little deflection. The observed average scattering angle can be explained only by considering multiple scattering. So it is wrong to ignore multiple scattering in the Thomson model. In Rutherford’s model, most of the scattering comes through a single collision and multiple scattering effects can be ignored as a first approximation.

Question 12.
The gravitational attraction between electron and proton in a hydrogen atom is weaker than the Coulomb attraction by a factor of about 10-40. An alternative way of looking at this fact is to estimate the radius of the first Bohr orbit of a hydrogen atom if the electron and proton were bound by gravitational attraction. You will find the answer interesting.
Answer:
If electron and proton were bound by gravitational attraction, then
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 10
It is astonishing this value of r is much greater than the size of the universe.

Question 13.
Obtain an expression for the frequency of radiation emitted when a hydrogen atom
de-excites from the level it to level (n – 1). For large it, shows that this frequency equals the classical frequency of revolution of the electron in the orbit.
Answer:
The energy of an electron in the nth orbit of a hydrogen atom is given by
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 11
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 12
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 13

i.e. frequencies are equal. This is called Bohr’s correspondence principle.

Question 14.
Classically, an electron can be in any orbit around the nucleus of an atom. Then what determines the typical atomic size? Why is an atom not, say, a thousand times bigger than its typical size? The question had greatly puzzled Bohr before he arrived at his famous model of the atom that you have learned in the text. To stimulate what he might well have done before his discovery, let us play as follows with the basic constants of nature and see if we can get a quantity with the dimensions of length that is roughly equal to the known size of an atom (~ 10-10m).
(a) Construct a quantity with the dimensions of length from the fundamental constants e, me, and c. Determine its numerical value.
(b) You will find that the length obtained in («) many orders of magnitude smaller than the atomic dimensions. Further, it involves c. But energies of atoms are mostly in a non-relativistic domain where c is not expected to play any role. This is what may have suggested Bohr discard c and look for something else’ to get the right atomic size. Now, the Planck’s constant h had already made its appearance elsewhere. Bohr’s great insight lay in recognizing that h, me, and e will yield the right atomic size. Construct a quantity with the dimension of length from h, mg, and e and confirm that its numerical value has indeed the correct order of magnitude.
Answer:
(a) Here, the dimensional formula of e is A1T1, the dimensional formula of me is M1, dimensional formula
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 14
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 15

Question 15.
The total energy of an electron in the first excited state of the hydrogen atom is about -3.4 eV.
(a) What is the kinetic energy of the electron in this state?
(b) What is the potential energy of the electron in this state?
(c) Which of the answers above would change if the choice of the zero of potential energy is changed?
Answer:
(a) K.E. = -E = – (-3.4 eV) = 3.4 eV
E. = 2E = 2 x (-3.4 eV)
= -6.8 eV
(b) Kinetic energy does not depend upon the choice of zero potential energy. Therefore, its value remains unchanged. However, the potential energy gets changed with the change in the zero levels of potential energy.

Question 16.
If Bohr’s quantisation postulate (angular momentum = nh/2π) is a basic law of nature, it should be equally valid for the case of planetary motion also. Why then do we never speak of quantization of orbits of planets around the sun?
Answer:
Applying Bohr’s quantization postulate,
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 15.1
i.e., n is very large. Since n is very large, the difference between the two successive energy or angular momentum levels is very small and the levels may be considered continuous.
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 16
Question 17.
Obtain the first Bohr’s radius and the ground state energy of a ‘muonic hydrogen atom’ (i.e. an atom in which a negatively charged muon (μ-1) of mass about 207 me orbits around a proton).
Answer:
Here the mass of the particle revolving around the proton is
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 17

We hope the NCERT Solutions for Class 12 Physics Chapter 12 Atoms, help you. If you have any query regarding NCERT Solutions for Class 12 Physics Chapter 12 Atoms, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 History Chapter 15 Framing the Constitution The Beginning of a New Era

NCERT Solutions for Class 12 History Chapter 15 Framing the Constitution The Beginning of a New Era are part of NCERT Solutions for Class 12 History. Here we have given NCERT Solutions for Class 12 History Chapter 15 Framing the Constitution The Beginning of a New Era.

Board CBSE
Textbook NCERT
Class Class 12
Subject History
Chapter Chapter 15
Chapter Name Framing the Constitution The Beginning of a New Era
Number of Questions Solved 8
Category NCERT Solutions

NCERT Solutions for Class 12 History Chapter 15 Framing the Constitution The Beginning of a New Era

Question 1.
What were the ideals expressed in the Objectives Resolution ?
Solution :
The “Objectives Resolution” outlined the ideals of the Constitution of Independent India as mentioned below :

  • Independent sovereign republic : India will be an independent state without any foreign or internal control. Its head will be elected by the people.
  • Justice, equality and freedom : It will guarantee its citizens justice, equality and freedom.
  • Safeguards for minorities : It assured that “adequate safeguards shall be provided for minorities, backward and tribal areas, and Depressed and Other Backward Classes”.

Question 2.
How was the term minority defined by different groups?
Solution :
N.G. Ranga, a socialist who had been a leader of the peasant movement, urged that the term minorities be interpreted in economic terms. The real minorities were the poor and the downtrodden. Some considered that the real minorities were the masses of our country who were so depressed and oppressed that they were ot even able to take advantage of the ordinary civil rights. Singh spoke eloquently on the need to protect the tribes, and ensure conditions that could help them come up to the level of the general population.

Question 3.
What were the arguments in favour of greater power to the provinces ?
Solution :
The following arguments were given in favour of greater power to the provinces :

  1. K. Santhanam stated that by giving more powers to the Centre, we could not make it strong because in such a situation, the Centre would be overburdened with responsibilities. It would not be able to function effectively. On the other hand, if the Centre was relieved of some functions or powers it could function effectively and become stronger.
  2. He argued that weak status would cripple them. Their financial position would be weaker and without finances they would not be able to take up any project for development. They would have to depend on the central aid for education, sanitation and other welfare work for the people. He added a strong centre might lead the states to “revolt against the Centre” in the future.
  3. A member from Orissa warned that “the Centre is likely to break” since powers had been excessively centralised under the Constitution.

Question 4.
Why did Mahatma Gandhi think Hindustani should be the national language?
Solution :
In view of Mahatma Gandhi Hindustani was a language that the common people could easily understand. Hindustani was a blend of Hindi and Urdu. It was also popular among a large section of the people. Moreover, it was a composite language enriched by the interaction of diverse cultures. Words and terms from many different languages got incorporated into this language over the years. It made this language easily understandable by people from various regions.
As per Mahatma Gandhi Hindustani would be the ideal language of communication between the communities. It would help to unify Hindus and Muslims and the people from north and south. Language came to be associated with the politics of religious identities from the end of the 19th century. But Mahatma Gandhi retained his faith in the composite character of Hindustani.

Question 5.
What historical forces shaped the vision of the Constitution?
Solution :
Historical forces that shaped the vision of the Constitution were as given below :

  1. Historic efforts in the past : Nehru in his famous speech of 13 December 1946 referred to the American and French Revolutions. He thus linked the making of the Indian Constitution with the revolutionary moments in the past. But at the same time he emphasised not to copy the west but to learn from their experiments, achievements and failures.
  2. The will of the people : Nehru stated that the source of the Constituent Assembly was its strength i.e., the will of the people. So, members always kept in mind that passions that lay in the hearts of the masses of the Indian people and tried to fulfil them. Thus, Constituent Assembly was expected to represent the people.
  3. India, a large country with diversities : India is a large country with different religions, castes, communities, languages and groups. It was necessary to keep all united. So, the Constitution was prepared keeping in mind these diversities.
  4. Protection of minorities : There were minorities and depressed classes. It was necessary to protect their interests. Gandhiji had already started movement for upliftment of the Harijan. Thus, there were debates in the Assembly and provisions were incorporated for their protection and upliftment.
  5. Period of violence : There were riots and violence and communal frenzy. Under these circumstances it was necessary to have a strong Centre. There were arguments in favour of and against it. But ultimately more powers were given to the Centre.
  6. Problem of princely states : There were more than five hundred princely states. To accommodate them, it was absolutely necessary to have a federal system of government.

Question 6.
Discuss the different arguments made in favour of protection of the oppressed groups.
Solution :
The different arguments made in favour of protection of the oppressed groups were as mentioned below :

  1. It was argued that the problem of the “Untouchables” could not be resolved through protection and safeguards alone. Their disabilities were caused by the social norms and the moral values of caste society that had used their services and labour but kept them at a social distance.
  2. J. Nagappa from Madras pointed out that the suffering of the Depressed Classes was i due to their systematic marginalisation and not due to their numerical insignificance. They had
    no access to education, or share in the administration.
  3. K.J. Khanderkar from the Central Provinces argued that the Depressed Classes had been suppressed for thousands of years to such an extent that their bodies and minds were not able to march forward.

Question 7.
What connection did some of the members of the Constituent Assembly make between the political situation of the time and the need for a strong Centre ?
Solution :
The Constitution of India was framed between December 1946 and December 1949. It was a trouble-some time. There were riots and violence. There was the rising of the ratings of the Royal India Navy in Bombay and other cities in the spring of 1946. The violence culminated in the massacres that accompanied the transfer of populations when the Partition of India was announced. Some members of the Constituent Assembly made connection between the above political situation of the time and the need for a strong Centre as mentioned below :

  1. Referring to riots and violence in the country, many members had repeatedly stated that the powers of the Centre had to be greatly strengthened to enable it to stop the communal frenzy.
  2. Gopalaswami Ayyangar declared that “the Centre should be made as strong as possible”.
  3. Balakrishna Sharma from the United Provinces reasoned at length that only a strong Centre could plan for the well-being of the country, mobilise the available economic resources and establish a proper administration.

Question 8.
How did the Constituent Assembly seek to resolve the language controversy ?
Solution :
There were two main views about the language of the nation as mentioned below :

  1. A plea for Hindi : R.V. Dhulekar, from the United Provinces made a strong plea that Hindi be used as the language of making the constitution. He wanted Hindi to be declared a National Language.
  2. The fear of domination : Shrimati Durgabai from Madras explained her worries. She informed the house that there was strong opposition against Hindi in the South. She stated
    that the erosion of inclusive and composite character of Hindustani was bound to create anxieties and fears amongst different language groups.

In view of the above differences, some members appealed for a spirit of accommodation and asked the members not to push the cause of Hindi aggressively. Thus, the language controversy was solved in the following way :

  • Hindi in the Devanagari script would be the official language.
  • Transition to Hindi would be gradual.
  • For the first fifteen years, English would continue to be used for all official purposes.
  • Each province was allowed to choose one of the regional languages for official work within the province.

Thus, referring to Hindi as the official rather that of the national language it was hoped that it would be acceptable to all.

We hope the NCERT Solutions for Class 12 History Chapter 15 Framing the Constitution The Beginning of a New Era help you. If you have any query regarding NCERT Solutions for Class 12 History Chapter 15 Framing the Constitution The Beginning of a New Era, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements

NCERT Class 12 Chemistry Solutions for Chapter 8  d-and f-Block Elements provides solutions to the questions provided in the textbook. These solutions are provided by the subject experts and are helpful for the students appearing for boards or competitive exams. The students can refer to these and enhance their conceptual knowledge.

NCERT Solutions are provided in the CBSE, MP, UP, and Gujarat boards. The students appearing for these boards can practice through the NCERT Solutions to score well in the examination.

Board CBSE
Textbook NCERT
Class Class 12
Subject Chemistry
Chapter Chapter 8
Chapter Name d-and f-Block Elements
Number of Questions Solved 48
Category NCERT Solutions

NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements

The chapter d and f block elements is very important from the examination perspective. It explains the elements in the groups 3-12. A detailed understanding of this chapter will help the students to differentiate between the characteristics of d and f block elements. It also explains a comparative account of lanthanoids and actinoids.

The NCERT Solutions for Class 12 Chemistry Chapter 8 provides in-depth details of d and f blocks elements. The students are advised to refer to these solutions for better results.

NCERT IN-TEXT QUESTIONS

Question 1.
Silver has completely filled d-orbitals (4d10) in its ground state. How can you say that it is a transition metal ?
Answer:
Silver (Z = 47) belongs to group 11 of (7-block (Cu, Ag, Au) and its outer electronic configuration is 4d105s1. It shows + 1 oxidation state (4d10 configuration) in silver halides (e.g. AgCl). However, it can also exhibit + 2 oxidation state (4d9 configuration) in compounds like AgF2 and AgO. Due to the presence of half filled d-orbital, silver is a transition metal.

Question 2.
In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomisation of zinc is the lowest, i.e., 126 kJ mol-1. Why?
Answer:
In 3d series from Sc to Zn, all elements have one or more unpaired e-1 s except Zn which has no unpaired electron as its outer EC is 3d104s2. Hence, the intermetallic bonding is weakest in zinc. Therefore, enthalpy of atomisation is lowest.

Question 3.
Which of the 3d series of transitional metals exhibits largest oxidation states and why?
Answer:
Mn (Z = 25) with electronic configuration [Ar]3d54s2 shows maximum oxidation state (+ 7) in its compounds since it has the maximum number of unpaired five i.e., seven. It shows largest variable oxidation state from + 2 to + 7 ( + 2, + 3, + 4, + 5, + 6, + 7) in its compounds.

Question 4.
The E°(M2+/M) value for copper is positive (+ 0·34 V). What is possibly the reason for this ? (C.B.S.E. Outside Delhi 2012, Sample Paper 2012)
Answer:
E°(M2+/M) for any metal is based upon three factors which have been discussed in the text part.
M(s) + ∆aH → M(g) ; (∆aH = Enthalpy of atomisation)
M(g) + ∆fH → M2+(g) ; (∆fH = Ionisation enthalpy)
M2+(g) + aq → M2+(aq); (∆hydH = Hydration enthalpy)
Copper has very high enthalpy of atomisation (energy required) and low enthalpy of hydration (energy released). In nut shell, the ∆fH i.e. ionisation enthalpy needed is not compensated by the energy released. Therefore E°(Cu2+/Cu) is positive.

Question 5.
How would you account for the irregular variation in ionisation enthalpies (first and second) in first series of transition elements ?
Answer:
The ionisation enthalpies of the transition metals are higher than those of s-block elements and less than the elements of p-block. Thus, these are less electropositive than the elements of s-block and at the same time more electropositive than the elements belonging to p-block present in the same period. In a transition series, the ionisation enthalpies increase from left to right. However, the gaps in the values of the two successive elements are not regular.

Question 6.
Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only?
Answer:
Oxygen and fluorine have small size and high electronegativity. Hence, they can oxidise the metal to the highest O.S.

Question 7.
Which is a stronger reducing agent Cr2+ or Fe2+ and why ? (SamplePaper 2011, C.B.S.E. Outside Delhi 2010, 2014)
Answer:
Cr2+ is a stronger reducing agent than Fe2+. This is quite evident from the E° values ;
E°Cr3+/Cr2+ = – 0-41 V and E°Fe3+/Fe2+ = 0-77 V.
Reason : d4 → d3 occurs when Cr2+ changes to Cr3+ ion while d6 → d5 takes place when Fe2+ gets converted to Fe3+ ion.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 1
Now, d4 → d3 transition is easier as compared to d6 → d5 transition because in the second case, an electron is removed from a paired orbital which is rather difficult. Therefore, Cr2+ is a stronger reducing agent than Fe2+.

Question 8.
Calculate the spin magnetic moment of M2+(aq) ion (Z = 27).
Answer:
Electronic configuration of element M(Z = 27) : [Ar] 3d74s2
Electronic configuration M2+ (aq) ion : 3d7 or NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 2
Magnetic moment of M2+ (aq) ion with n = 3 ; \(\mu =\sqrt { n\left( n+2 \right) } \)
\(=\sqrt { 3\left( 3+2 \right) } =\sqrt { 15 } =3\cdot 87BM.\)

Question 9.
Explain why Cu+ ion is not stable in an aqueous solution. (C.B.S.E. Delhi 2011)
Answer:
In aqueous solution Cu+ (aq) undergoes disproportionation to form Cu2+ (aq) ion and Cu.
2Cu+(aq) → Cu2+(aq) + Cu(s)
The higher stability of Cu2+ (aq) in an aqueous solution may be attributed to its greater negative ∆hydH than that of Cu+ (aq). It compensates for the second ionisation enthalpy of Cu involved in the formation of Cl2+ ion. Thus, Cu+ (aq) ion changes to Cu2+ (aq) ion which is more stable.

Question 10.
Actinoid contraction is greater from element to element than lanthanoid contraction. Why?
Answer:
This is due to poor shielding by 5f-electrons in the actinoids than that by 4f e-1s in lanthanoids.

NCERT EXERCISE

Question 1.
Write down the electronic configuration of :
(a) Cr3+
(b) Cu+
(c) Co2+
(d) Mn2+
(e) Pm3+
(f) Ce4+
(g) Lu2+
(h) Th4+
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 3

Question 2.
Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their+3 state?
Answer:
A half-filled d orbital or a completely filled d orbital is more stable than any other state. Mn2+ already has a half-filled stable state hence would not undergo oxidation to form Mn+3. On the other hand, Fe2+ on oxidation to Fe3+ will have half-filled d orbitals which are more stable.

Question 2.
Why are Mn2+ compounds more stable than Fe2+ compounds towards oxidation to their +3 state?
Answer:
Electronic configuration of Mn2+ is 3d5 while that of Fe2+ is 3d6. This shows that the Fe2+ ion has an urge to change to Fe3+ ion by losing an electron whereas the Mn2+ ion has no such tendency. Thus, the + 2 oxidation state of Mn is more stable as compared to the + 2 oxidation state of Fe.

Question 3.
Explain briefly how + 2 oxidation state becomes more and more stable in the first half of the first-row transition elements with increasing atomic number.
Answer:
In all the elements listed, with the removal of valence 45 electrons (+2 oxidation state), the 3d-orbitals get gradually occupied. Since the number of empty d-orbitals decreases or the number of unpaired electrons in 3d orbitals increases, the stability of the cations (M2+) increases from Sc2+to Mn2+.

Question 4.
To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with an example.
Answer:
In the transition series, the oxidation states which lead to exactly half-filled or completely filled d-orbitals are more stable. For example, the electronic configuration of Fe(Z = 26) is [Ar] 3d64s2. It shows various oxidation states but Fe (III) is most stable because it has the configuration [Ar]3d5.

Question 5.
What must be the stable oxidation state of the transition elements with the following electronic configuration in the ground states of their atoms: 3d3, 3d5, 3d8, 3d4?
Answer:
The maximum oxidation states of reasonable stability in the transition metals of 3d series correspond to the sum of s and d-electrons upto Mn. However, after Mn there is an abrupt decrease in oxidation states. In the light of this, most stable oxidation states of the elements are:
3d3 : 3d3s2 (+ 5);3 : 3d54s1 (+ 6) and 3d54s2 (+ 7)
3d8 : 3d84s2 (+ 2); 3d4 : 3d44s2 or 3d54s1 (+6)

Question 6.
Name the oxometal anions in the first transition series of transition metals in which the metal exhibits an oxidation state equal to its group number.
Answer:
Vanadate: VO3
chromate: CrO42-
permanganate: MnO4

Question 7.
What is lanthanoid contraction? What are the consequences of lanthanoid contraction? (C.B.S.E. Delhi 2013)
Answer:
One common property associated with the elements in the periodic table is the variation in their atomic and ionic radii down the group and along a period. In general, these increase down the group due to the increase in the number of shells and decrease along a period considerably because of the increase in the magnitude of the effective nuclear charge.
Consequences of Lanthanoid Contraction
(a) Separation of Lanthanoids: Separation of lanthanoids is possible only due to lanthanoid contraction. All the lanthanoids have quite similar properties and due to this reason, they are difficult to separate. However, because of lanthanoid contraction, their properties (such as ionic size, ability to form complexes etc.,) vary slightly.

(b) Variation in basic strength of hydroxides: The basic strength of oxides and hydroxides decreases from La(OH)3 to Lu(OH)2. Due to lanthanoid contraction, size of M3+ ions decreases and thus there is a corresponding increase in the covalent character in M—OH bond. The acidic strength which involves the cleavage of the O—H bond follows the reverse trend i.e. it increases along the series.

(c) Similarly in the atomic sizes of the elements of the second and third transition series present in the same group: We know that the atomic sizes of the elements generally increase appreciably down a group. Similar trend is also expected in the elements present in the different groups of d-block.

(d) Variation in standard reduction potential: Due to lanthanoid contraction there is a small but steady increase in the standard reduction potential (E°) for the reduction process.
M3+ (aq) + 3e → M (aq)

(e) Variation in physical properties like melting point, boiling point, hardness etc: Various physical properties like m.pt., b.pt., hardness etc., increase with the increase in atomic number. This is because the attraction forces between the atoms increase as the size decreases.

Question 8.
What are the characteristics of transition elements and why are they called transition elements? Which of the d- block elements may not be regarded as the transition elements?
Answer:
In the transition elements, d-orbitais are successively filled. The general electronic configuration of transition elements is (n – 1) d1-10 ns1-2. There are three transition series. The first transition series involves the filling of 3d-orbitais. It starts from scandium (Z = 21) and goes upto zinc (Z = 30).

The second transition series involves the filling of 4 d-orbitais and includes 10 elements from yttrium (Z = 39) to cadmium (Z = 48). The third transition series invokes the filling of 5d-orbitals. The first element of this series lanthanum (Z = 57). It is followed by fourteen elements called lanthanides which involve the filling of 4f-orbitais. The net nine elements from hafnium (Z = 72) to mercury (Z = 80) belong to the third transition series.

There is an incomplete fourth transition series. it involves the filling of 6d- subshell starting from actinium (Z = 89) followed by elements with atomic number 104 onwards.

Question 9.
In what way is the electronic configuration of the transition elements different from that of the non-transition elements?
Answer:
Transition elements contain partially filled d-orbitals whereas non-transition elements have no d-orbitals or have completely filled d -orbitals.

Question 10.
What are the different oxidation states exhibited by lanthanoids?
Answer:
+3 is the common oxidation state of the lanthanoids.
In addition to +3, oxidation states +2 and +4 are also exhibited by some of the lanthanoids.

Question 11.
Explain giving the reason:
(a) Transition metals and many of their compounds show paramagnetic behaviour. (H.P. Board 2014)
(b) The enthalpies of atomisation of transition metals are high. (Jharkhand Board 2010, C.B.S.E. Outside Delhi 2008, 2012, H.P. Board 2014)
(c) The transition metals generally form coloured compounds. (C.B.S.E. 2010. 2012)
(d) The transition metals and their compounds act as good catalysts. (C.B.S.E.Outside Delhi 2010) (C.B.S.E. Delhi 2008, Sample Paper 2010, H.P. Board 2017)
Answer:
(i) Paramagnetic arises due to the presence of unpaired electrons, each such electron has a magnetic moment associated with it due to its spin angular momentum. Transition metals have in its ground state or ionized state has a number of unpaired d-electrons which gives them a paramagnetic behaviour.

(ii) Transition metals have very high interatomic metallic interaction due to the involvement of greater number of electrons from (n – l)d in addition to the ns electrons. The greater the number of valence electrons, the stronger is the resultant bonding due to the greater overlapping of half-filled orbitals. Hence, more amount of energy is required to break these metallic bonds. Thus enthalpy of atomisation of transition metal is very high.

(iii) Colour of transition metal – compounds is due to the excitation of an electron from a lower energy d-orbital to a higher energy d orbital. The energy of excitation corresponds to the frequency of light absorbed and the colour observed corresponds to the complementary colour of the light absorbed (whose frequency lies on the visible region). The frequency of the light absorbed depends on the nature of ligand. Transition metals form coloured compounds due to the presence of vacant d-orbitals for the d-d transition of e’ which causes the colour.

(iv) The catalytic activity of transition metals is ascribed to their ability to adopt multiple oxidation states and to form complexes. Catalyst at a solid surface involve the formation of bonds between reactant molecules and atoms of the surface of the catalyst this has the effect of increasing the concentration of the reactants at the catalyst surface and also weakening of the bonds in the reacting molecules (activation energy is lowered. Transition metals have d and s orbitals to from these bonds.

Question 12.
What are interstitial compounds? Why are such compounds well known for transition metals?
Answer:
Interstitial compounds are the compounds formed as a result of the trapping of atoms of small elements like H, N, C, B etc. in the crystal lattices of certain metals. These are non-stoichiometric in nature and are neither ionic nor covalent. In fact, no proper bonds exist in the atoms of metals and non-metals involved in these compounds. Transition metals have a tendency to form such compounds. A few examples are: TiC,
Mn4N, Fe3H, VH0·56, Vse0·98 and Fe0·94O etc.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 4

  1. These are generally non-stoichiometric in nature. Therefore, they cannot be represented by a definite structure or formula.
  2. The compounds are neither covalent nor ionic and they don’t represent the normal oxidation states of the metals.
  3. Since the strengths of the metallic bonds in these compounds increase due to greater electronic interactions, they show high melting points and high metallic conductivity. However, these compounds are chemically inert.
  4. The conductivity of the metals remains unaffected in the corresponding interstitial compounds.

Question 13.
How is the variability in oxidation states of transition metals different from that of non-transition metals? Illustrate with examples.
Answer:
The variability of oxidation states, characteristics of transition elements arises out of incomplete filling of d orbitals in such a way that their oxidation states differ from each other by unity This is in contrast with the variability of oxidation states of non-transition elements where oxidation states normally differ by a unit of two.
eg: Vanadium: V+2, V+3, V+4, V+5
Chromium : Cr+2, Cr+3, Cr+4, Cr+5, C+6
Nitrogen: +5, +3, +1, -1, -3.

Question 14.
Describe the preparation of potassium dichromate from chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?
Answer:
Preparation from chromite:
Potassium dichromate is generally prepared from chromite ore (FeCr2O4). It is in fact, a mixed oxide Fe0.Cr2O3 of iron and chrome also called ferrochrome or chrome iron.
(i) Conversion of chromite ore into sodium chromate: Chromite ore is fused with sodium hydroxide or sodium carbonate in the presence of air.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 5
(ii) Conversion of sodium chromate into sodium dichromate :
The fused mass obtained above is extracted with water. Sodium chromate which is soluble in water goes into the solution leaving behind the insoluble ferric oxide (Fe2O3). The yellow solution of sodium chromate obtained above is treated with concentrated H2SO4 to form sodium dichromate which has an orange colour.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 6
(iii) Conversion of sodium dichromate into potassium dichromate:
Sodium dichromate is more soluble and less stable than potassium dichromate.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 7
Effect of increasing pH : The solution of potassium dichromate (K2Cr2O7) in water is orange in colour. On increasing the pH i.e. on adding the base, the potassium dichromate changes to potassium chromate (K2CrO4) which is yellow in colour. Thus, on increasing the pH, the colour of the solution changes from orange to yellow.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 8

Question 15.
Describe the oxidising action of potassium dichromate and write the ionic equations for its reaction with:
(a) iodide,
(b) iron (II) solution
(c) H2S.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 9
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 10
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 11

Question 16.
Describe the preparation of potassium permanganate. How does acidified permanganate solution react with:
(a) iron (II) solution
(b) SO2
(c) oxalic acid?
Write the ionic equations for the reactions.
Answer:
Potassium permanganate is prepared on a large scale from the mineral pyrolusite, MnO2.
2MnO2 + 4KOH + O2 → 2K2MnO4 + 2H2O
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 12

Question 17.
For M2+/M and M3+/M2+ systems, the E° values of some metals are given :
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 13
Use this data to comment upon :
(a) The stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+.
(b) The ease with which iron can be oxidised as compared to the similar process for either chromium or manganese metal.
Answer:
As \({ E }_{ { Cr }^{ 3+ }/{ Cr }^{ 2+ } }^{ \circ }\) is negative (-0·4 V), this means that Cr3+ ions in solution cannot be reduced to Cr2+ ions or Cr3+ ions are very stable. As farther comparison of E° values shows that Mn3+ ions can be reduced to Mn2+ ion more readily than Fe3+ ions. Thus, in the light of this, the order of relative stabilities of different ions is Mn3+ < Fe3+ < Cr3+.
(b) From the E° values, the order of oxidation of the metal to the divalent cation is Mn > Cr > Fe.

Question 18.
Predict which of the following will be coloured in an aqueous solution? Ti3+, V3+,Cu+, Sc3+, Mn2+, Fe3+ and Co2+ Give reasons for each.
Answer:
Among the above mentioned, ions Ti3+, V3+ Mn2+, Fe3+, CO2+ will be coloured in its aqueous solution due to the ability of e’ to jump from a lower energy d orbital to a higher energy d orbital. In case of the ions Cu+, Sc3+ this d-d transition cannot take place either due to the absence of any e- in 3d orbital or due to complete filling of d orbital.

Question 19.
Compare the stability of the +2 oxidation state for the elements of the first transition series.
Answer:
The common oxidation state of 3d series elements is + 2 which arises due to the participation of only 4s electrons. The tendency to show the highest oxidation state increases from Sc to Mn then decreases due to the pairing of electrons in 3d subshell. Thus in the series Sc(II) does not exist, Ti(II) is less stable than Ti(IV). At the other end of the series, the oxidation state of Zn is +2 only.

Question 20.
Compare the chemistry of actinoids with that of the lanthanoids with special reference to:
(i) electronic configuration
(ii) atomic and ionic sizes and
(iii) oxidation state
(iv) chemical reactivity.
Answer:
(i) Electronic configuration:
The general electronic configuration for lanthanoids is [Xe] 0-14 5d 0-1 6s2 and that of actinoids is [Rn] 5f 0-14 6d0-1 7s2. Unlike 4f orbitals, 5 f orbitals are not deeply buried and participate in bonding to a greater extent.

(ii) Oxidation states:
The principal oxidation state of lanthanoids is (+3). However, sometimes we also encounter oxidation states of +2 and +4. This is because of extra stability of fully-filled and half-filled orbitals. Actinoids exhibit a greater range of oxidation states. This is because the 5f, 6d and 7s levels are of comparable energies. Again, (+3) is the principal oxidation state for actinoids. Actinoids such as lanthanoids have more compounds in +3 state than in +4 state.

(iii) Atomic and ionic size Similar to lanthanoids, actinoids also exhibit actinoid contraction overall decrease in atomic and ionic radii. The contraction is greater due to the poor shielding effect of 5f orbitals. Hence there is an unexpected in the atomic and ionic sizes of actinoids.

(iv) Chemical activity
In the lanthanide series, the earlier members of the series are more reactive. They have reactivity that is comparable to Ca. With an increase in the atomic number, the lanthanides start behaving similar to Al. Actinoids, on the other hand, are highly reactive metals, especially when they are finely divided. When they are added to boiling water, they give a mixture of oxide and hydride. Actinoids combine with most of the non-metals at moderate temperatures. Alkalies have no action on these actinoids. In the case of acids, they are slightly affected by nitric acid (because of the -formation of a protective oxide layer).

Question 21.
How would you account for the following :
(a) Of the d4 species, Cr2+ is strongly reducing while Mn3+ is strongly oxidising in nature.
(b) Cobalt (II) is stable in aqueous solution but in the presence of complexing reagents, it is easily oxidised.
(c) d1 configuration is very unstable in ions.
Answer:
(a) E° value of Cr3+/Cr2+ is negative (-0·41 V) while that of Mn3+/Mn2+ is positive (+ 1·57 V). This means Cr2+ ions can lose electrons to form Cr3+ ions and act as a reducing agent while Mn3+ ions can accept electrons and can act as oxidising agent.
(b) Cobalt (II) is stable in aqueous solution but in the presence of complexing agent, it undergoes change in oxidation state from +2 to +3 and is easily oxidised.
(c) The ion with d1 configuration is expected to be extremely unstable and has a great urge to acquire d° configuration (very stable) by losing the only electron present in the d-subshell.

Question 22.
What is meant by ‘disproportionation’ ? Give two examples of disproportionation reaction in aqueous solution.
Answer:
In a disproportionation reaction, an element undergoes an increase as well as decrease in its oxidation state forming
two different compounds. In other words, we can say that it can act both as reducing agent as well as oxidising agent.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 14

Question 23.
Which metal in the first series of transition metals exhibits + 1 oxidation state most frequently and why?
Answer:
Copper, because with +1 oxidation state an extra stable configuration, 3d10 results.

Question 24.
Calculate the number of unpaired electrons in the following gaseous ions :
Mn3+, Cr3+, V3+.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 15

Question 25.
Give examples and suggest reasons for the following features of the transition metal chemistry:
(i) The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.
(ii) A transition metal exhibits the highest oxidation state in oxides and fluorides.
(iii) The highest oxidation state is exhibited in oxoanions of a metal.
Answer:
(i) In case of a lower oxide of a transition metal, the metal atom has a low oxidation state. This means that some of the valence electrons of the metal atoms are not involved in bonding. As a result, it can donate electrons and behave as a base.

On the other hand, in the case of a higher oxide of a transition metal, the metal atom has a high oxidation state. This means that the valence electrons are involved in bonding. As a result, it can accept electrons and behave as an acid. For example, MnIIO is basic and MnVIIO is acidic.

(ii) Oxygen and fluorine act as strong oxidising agents because of their high electronegativities and small sizes. Hence, they bring out the highest oxidation states from the transition metals. In other words, a transition metal exhibits oxidation states in oxides and fluorides. For example, in OsF6 and V2O5, the oxidation states of Os and V are + 6 and respectively.

(iii) Oxygen is a strong oxidising agent due to its high electronegativity and small size so, oxoanions of metal have the highest oxidation state. For example, in MnO4, the oxidation state of Mn is +7.

Question 26.
Give the steps in the preparation of (C.B.S.E. Delhi 2009 comptt.)
(a) K2Cr2O7 from chromite ore
(b) KMnO4 from pyrolusite ore.
Answer:
(a)
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 16
(b)
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 17

Question 27.
What are alloys? Name an important alloy which contains some of the lanthanoid metals. Mention its uses.
Answer:
An alloy is a homogeneous mixture of two or more metals or metals and non-metals. An important alloy that contains lanthanoid metal is mischmetal which contains 50% Cerium and 25 % Lanthanum, with small amounts of Nd (Neodymium) and Pr (Praseody-mium). It is used in Mg-based alloy to produce bullets, shells, and lighter flints.

Question 28.
What are inner transition elements? Decide which of the following atomic numbers belong to inner transition elements :
29, 59, 74, 95, 102, 104.
Answer:
The inner transition elements also called/-block elements include the series of lanthanoids (Z = 58 to 71) and actinoids (Z = 90 to 103). This means that the elements with atomic numbers 59, 95, and 102 belong to inner transition elements.

Question 29.
The chemistry of actinoid elements is not so smooth as that of lanthanoids. Justify this statement by giving some examples of the oxidation states of these elements.
Answer:
Lanthanoids show a limited number of oxidation states, such as +2, +3 and +4 (+3 is the principal oxidation state). This is because of large energy gap between 5d and 4f- subshells. On the other hand, actinoids also show a principal oxidation state of +3 but show a number of other oxidation state also. For example, Uranium (Z = 92) exhibits oxidation states of +3, +4, +5, +6 and Neptunium (Z = 94) shows oxidation states of +3, +4, +5, +6 and +7. This is because of small energy difference between 5f and 6d orbitals.

Question 30.
Which is the last element in the series of actinoids? Write the electronic configuration of the element. Comment upon its possible oxidation state.
Answer:
Lawrencium (Lr = 103); [Rn] 5f146d17s2 oxidation state = +3.

Question 31.
Use Hund’s rule to derive the electronic configuration of Ce3+ ion and calculate its magnetic moment on the basis of the spin-spin formula.
Answer:
Cerium electronic configuration = [Xe]4f1 5d1 16s2
Ce+3 ion = [Xe]4f1
i.e., one unpaired electron is present
Magnetic moment, µ = \(\sqrt{n(n+2)}\) = \(\sqrt { 3 }\) = 1.73BM.

Question 32.
Name the members of the lanthanoid series which exhibit+4oxidatk>nstatesandthosewhichexhibit +2 oxidation states. Try to correlate this type of behaviour with the electronic configurations of these elements.
Answer:
+ 4 oxidation state in Ce (Z = 58), Pr (Z = 59), Tb (Z = 65).
+ 2 oxidation state in Nd (Z = 60), Sm(Z=62), Eu (Z = 63), Tm (Z=69), Yb (Z = 70).
+ 2 oxidation state is exhibited when the lanthanoid has the configuration 5cf 6s2 so that two electrons are-easily lost.
+ 4 oxidation state is exhibited by the elements which after losing four electrons acquire configuration 4f° or 4f1

Question 33.
Compare the chemistry of the actinoids with that of lanthanoids with reference to:
(i) electronic configuration
(ii) oxidation states and
(iii) chemical reactivity.
Answer:
(i) Electronic configuration:
The general electronic configuration for lanthanoids is [Xe] 0-14 5d 0-1 6s2 and that of actinoids is [Rn] 5f 0-14 6d0-1 7s2. Unlike 4f orbitals, 5 f orbitals are not deeply buried and participate in bonding to a greater extent.

(ii) Oxidation states:
The principal oxidation states of lanthanoids is (+3). However, sometimes we also encounter oxidation states of +2 and +4. This is because of extra stability of fully-filled and half-filled orbitals. Actinoids exhibit a greater range of oxidation states. This is because the 5f, 6d and 7s levels are of comparable energies. Again, (+3) is the principal oxidation state for actinoids. Actinoids such as lanthanoids have more compounds in the +3 state than in the +4 state.

(iii) Atomic and ionic size Similar to lanthanoids, actinoids also exhibit actinoid contraction overall decrease in atomic and ionic radii. The contraction is greater due to the poor shielding effect of 5f orbitals. Hence there is an unexpected in the atomic and ionic sizes of actinoids.

(iv) Chemical reactivity
In the lanthanoid series, the earlier members of the series are more reactive. They have reactivity that is comparable to Ca. With an increase in the atomic number, the lanthanides start behaving similar to Al. Actinoids, on the other hand, are highly reactive metals, especially when they are finely divided. When they are added to boiling water, they give a mixture of oxide and hydride. Actinoids combine with most of the non-metals at moderate temperatures. Alkalies have no action on these actinoids. In the case of acids, they are slightly affected by nitric acid (because of the -formation of a protective oxide layer).

Question 34.
Write the electronic configuration of the elements with atomic numbers 61, 91, 101, 109.
Answer:
Promethium or Pm (Z = 61) [Xe]544f55d06s2
Protactinium or Pa (Z = 91) [Rn] 4f26d17s2
Mendelevium or Md (Z = 101) [Rn] 5f16d07s2
Meitnerium or Mt (Z = 109) [Rn] 5f146d77s2

Question 35.
Compare the general characteristics of the first transition series of transition metals with those of the second and third transition series metals in the respective vertical columns. Give special emphasis on the following points :
(i) electronic configuration
(ii) oxidation states
(iii) ionisation enthalpies
(iv) atomic sizes.
Answer:
(i) Electronic configuration. There are some exceptions in the electronic configurations in all the three series.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 18
(ii) Oxidation state. The elements belonging to the different series but present in the same group have similar electronic configurations and therefore, exhibit almost same variable oxidation states. In general, these are maximum in the middle of the series while minimum towards the end. Transition elements show variable oxidation states due to the participation of ns and (n – 1) d electrons in bonding because the energies of ns and (n – 1) d-subshells are quite close. The stability of a particular oxidation state depends upon the nature of the element with which the transition metal forms the compound.

(iii) Ionisation enthalpies. In general, the ionisation enthalpies in all three transition series increase from left to the right. However, the gaps in the two successive elements in a particular series are small and are also not regular. The first three ionisation enthalpies of the elements present in the first transition series are given in the text part. The ∆iH1 [ values of the elements belonging to the 5d series and higher as compared to those belonging to 3d and Ad series in the same group because of poor shielding by intervening 4f electrons present.

(iv) Atomic size. In all three transition series, the atomic, as well as ionic radii of the elements, increase from left to right. The values for 3d series are given in the text part. However, the increase in their values is not as much as expected since the shielding by (n – 1 )d electrons is not as much as expected. In a particular group, the atomic radius of the elements belonging to Ad series is more than the elements in the 3d series. However, the gaps in the elements belonging to Ad and 5d series are negligible on account of lanthanoid contraction which the elements of the 5d experience.

Question 36.
Write down the number of 3d electrons in each of the following ions :
Ti2+, V2+, Cr3+, Mn2+, Fe2+, Fe3+, Co2+, Ni2+ and Cu2+.
Indicate how would you expect the five 3d orbitals to be occupied for these hydrated ions (octahedral).
Answer:
The number of 3d electrons in the ions are :
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 19
For the explanation of the involvement of 3d orbitals in the hydrated ions (octahedral in nature) consult the next unit on coordination compounds.

Question 37.
Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.
Answer:
The properties of the elements of the first transition series differ from those of the heavier transition elements in many ways.
(i) The atomic sizes of the elements of the first transition series are smaller than those of the heavier elements of the 2nd and 3rd transition series). However, the atomic sizes of the elements in the third transition series are virtually the same as those of the corresponding members in the second transition series this is due to lanthanoid configuration.

(ii) +2 and +3 oxidation states are more common for elements in the first transition series, while higher oxidation states are more common for the heavier elements.

(iii) The enthalpies of atomization of the elements in the first transition series are lower than those of the corresponding elements in the second and third transition series.

(iv) The melting and boiling points of the first transition series are lower than those of the heavier transition elements. This is because of the occurrence of strong metallic bonding (M – M bonding)

(v) The dements of the first transition series from low-spin or high-spin complexes depending upon the strength of the ligand field. However, the heavier transition elements form only low-spin complexes, irrespective of the strength of the ligand field.

Question 38.
What can be inferred from the magnetic moment values of the following complex species?
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 20
Answer:
The magnetic moment of a compound is given by the relation (µ) = \(\sqrt { n\left( n+2 \right) } \) B.M, where n is the number of unpaired electrons.
For one unpaired electron (n = 1) ; µ = \(\sqrt { 1\left( 1+2 \right) } =\sqrt { 3 } =1\cdot 73\quad B.M.\)
For two unpaired electrons (n – 2) ; µ = \(\sqrt { 2\left( 2+2 \right) } =\sqrt { 8 } =2\cdot 83\quad B.M.\)
For three unpaired electrons (n = 3); µ = \(\sqrt { 3\left( 3+2 \right) } =\sqrt { 15 } =3\cdot 87\quad B.M.\)
For four unpaired electrons (n = 4) ; µ = \(\sqrt { 4\left( 4+2 \right) } =\sqrt { 24 } =4\cdot 9\quad B.M.\)
For five unpaired electrons (n = 5) ; µ = \(\sqrt { 5\left( 5+2 \right) } =\sqrt { 35 } =5\cdot 92\quad B.M.\)
*In the light of the above value, let us gather the desired information about the complex species that are mentioned
(i) K4[Mn(CN)6]
Oxidation state of Mn : [Mn(CN)6]4- , x + 6(-l) = -4 or x = -4 + 6 = + 2
The magnetic value of 1·73 B.M. indicates the presence of one unpaired electron in the complex. When six, CN ions (or ligands) approach Mn2+ ion, electrons in 3d orbitals pair up to make available six vacant orbitals involving d2sp3 hybridisation.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 21
The complex is octahedral and is paramagnetic due to one unpaired electron.
(ii) [Fe(H2O)6]2+
Oxidation state of Fe : [Fe(H2O)6]2+ ; r + 6 (0) = +2
The magnetic moment value of 5·3 B.M. indicates that there are four unpaired electrons in the complex. This means that the electrons in Fe2+ ion do not pair up when six H20 molecules (or ligands) approach it. Since the desired number of vacant orbitals (six) are available, die complex formed is sp3d2 hybridised.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 22
The complex is octahedral and is paramagnetic due to four unpaired electrons. It is also called outer orbital complex because 4d (n = 4) orbitals are involved.
(iii) K2[MnCl4]
Oxidation state of Mn : [MnCl4]2-, x + 4(-1) = -2 or x = -2 + 4= + 2
The magnetic moment value of 5·9 B.M. indicates that there are five unpaired electrons in the complex. This means that all the five 3d orbitals in Mn2+ ion are involved in the bond formation. The complex is sp3 hybridized in which one vacant 4s and three vacant 4p orbitals participate.
NCERT Solutions for Class 12 Chemistry Chapter 8 d-and f-Block Elements 23
The complex is therefore, tetrahedral in nature.

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NCERT Solutions for Class 12 History Chapter 12 Colonial Cities Urbanisation, Planning and Architecture

NCERT Solutions for Class 12 History Chapter 12 Colonial Cities Urbanisation, Planning and Architecture are part of NCERT Solutions for Class 12 History. Here we have given NCERT Solutions for Class 12 History Chapter 12 Colonial Cities Urbanisation, Planning and Architecture.

Board CBSE
Textbook NCERT
Class Class 12
Subject History
Chapter Chapter 12
Chapter Name Colonial Cities Urbanisation, Planning and Architecture
Number of Questions Solved 9
Category NCERT Solutions

NCERT Solutions for Class 12 History Chapter 12 Colonial Cities Urbanisation, Planning and Architecture

Question 1.
To what extent are census data useful in reconstructing patterns of urbanisation in the colonial context ?
Solution :
The census data are useful in reconstructing patterns of urbanisation in the colonial context in the following ways :

  1. The censuses reveal that after 1800 the urbanisation in India was slow. The proportion of the urban population to the total population in India was almost stagnant. Between 1900 and 1940 the urban population increased from about 10 per cent of the total population to about 13 per cent.
  2. Smaller towns did not grow economically but Bombay, Madras and Calcutta grew rapidly.
  3. The introduction of railways changed the centre of economic activity from traditional towns to towns connected with the railways.

The above facts provide us the patterns of urbanisation but the historians have found the census data misleading because the census operation was a means by which social data were converted into convenient statistics about the population. There were many shortcomings in it. For example, classification of different sections of population was arbitrary. There were overlapping identities of people. People w7ere too suspicious of census operations and did not cooperate with the officials. Thus, census data is invaluable but should be studied carefully in restructuring patterns of urbanisation in colonial India.

Question 2.
What do the terms “White” and “Black” Town signify?
Solution :
The British had white skin as they were often described ‘white’ and they considered themselves as superior to others. On the other hand, the blacks had brown or black skin. So they were known as the ‘black’. The White signified their superiority over the black due to the colour of their skin. The British symbolised the Black areas full of chaos and anarchy, filth and disease and on the other hand, the white areas stood for cleanliness and hygiene. In Black areas, epidemics like cholera and plague often broke out. So the British took stringent measures to ensure sanitation and public health to prevent diseases of the Black areas. They ensured underground piped water supply and introduced sewerage and drainage system in White areas. Thus, we can say, the White Towns were those parts of the colonial towns where the White people lived. These towns had wide roads, barracks, churches, paradeground, big bungalows and gardens, symbolised settled city life, whereas the Indian lived in Black Towns, were said to be unorganised and a source of filth and disease.

Question 3.
How did prominent Indian merchants establish themselves in the colonial city?
Solution :
The prominent Indian merchants established themselves in the colonial city in the following ways :

  1. With the expansion of railways, the countryside from where raw materials and labour were obtained was linked to the cities like Bombay, Madras and Calcutta. This gave an opportunity to the Indian merchants to set up modern factories. Thus, after the 1850s, cotton mills were set up by Indian merchants and entrepreneurs in Bombay.
  2. Kanpur specialised in leather, woollen, cotton textiles and Jamshedpur where steel factory was established by J. Tata, specialised in steel.
  3. The American Civil War started in 1861 gave another opportunity to the Indian merchants for earning huge profits. Bombay was the most important city of India. By the late nineteenth century, Indian merchants in Bombay established cotton mills.

Question 4.
Examine how concerns of defence and health gave shape to Calcutta.
Solution :
Sirajudaula, the Nawab of Bengal in 1756, sacked the small fort from Britisher. In this fort the British traders had built to house their goods. Consequently, when Sirajudaula was defeated in the Battle of Plassey, the British built a new fort, Fort William which could not be easily attacked. Around this a vast open space was left. This open space ‘ was called the Maidan or garermath. This was done for security reasons, because there would be no obstructions to a straight time of fire from the Fort against an advancing enemy army. Soon the British began to move out of the Fort. They built residences along the periphery of the Maidan. This indicates that how the English Settlement in Calcutta began to take shape. The vast open space around the Fort William became the significant town planning measure in Calcutta (Now Kolkata).

Lord Wellesley was more concerned about the conditions that existed in the cities. Cities were overcrowded, and had no sanitation facilities. He issued an administrative order in 1803 on the need for town planning and set up various committees for this purpose open places in the city would make the city healthier. As a result of this, many bazaars, ghats, burial ground and tanneries were cleared or removed. After Wellesley’s departure, the Lottery Committee carried on with the work of town planning in Calcutta.

Question 5.
What are the different colonial architectural styles which can be seen in Bombay city ?
Solution :
The different colonial architectural styles which can be seen in Bombay city are as mentioned below :

  1. European style : In mid nineteenth century, the buildings were constructed in the European style to create a familiar landscape in an alien country and to symbolise their superiority.
  2. Indian style : As the Indians used European architecture, the British adopted Indian style that can be seen in the construction of bungalows in Bombay and all over India.
  3. Neo-classical or new classical style : Its characteristics are construction of geometrical structures fronted with lofty pillars. Town Hall is an example of this style.
  4. Neo-Gothic style : Its characteristics are high-pitched roofs, pointed arches and detailed decoration: Secretariat, University of Bombay and High Court were made in this style. The most spectacular example of the neo-Gothic style is the Victoria Terminus.
  5. Indo-saracenic style : It was a hybrid architectural style that combined the Indian with the European. It was inspired by the medieval buildings in India with their domes, chhatris, jalis and arches. The Gateway of India and the Taj Mahal Hotel that was built by Jamsetji Tata belong to this style.

Question 6.
How were urban centres transformed during the eighteenth century?
Solution :
(i) The disintegration of the mughal empire after the death of Aurangzab paved the way of emergence of paverful regional powers. The capital cities of these regional kingdom likes Lucknow, Poona, Nagpur and Barda now become important. Taking the advantage of this opportunity many nobles and officials created new urban settlements such as the qasbah and ganj.

(ii) The European companies too had set up their bases in different parts of India during the sixteenth and seventeenth centuries. For example the Portugues (in Panaji in 1570) and the British in Madras in 1639. With the expansion in commercial activity, towns began to emerge as trading centres.

(iii) From the mid-eighteenth century trading. Centres like Surat and Dhakha which had grown in the seventeenth century now began to decline as trade shifted to other places. When the British acquired Bengal and the east Indian’s Company’s trade hereafter expanded the colonial port cities likes Madras and Calcutta. These new part cities began to emerge as the new economic capitals.

(iv) In these newly developed cities many new buildings were built and new occupations developed. People flocked to these cities in large numbers. By the nineteenth century, these newly developed cities become the biggest cities in India.

Question 7.
What were the new kinds of public places that emerged in the colonial city ? What functions did they serve ?
Solution :
New kinds of public places that emerged in the colonial city were as given below :

  1. Fort St. George (Madras), Fort William (Calcutta), the Fort George (Bombay). These were the fortified areas of British settlement.
  2. The Writers’ Building in Calcutta : It was the building where the servants of the East India Company in India stayed on arrival in the country. Later this building became a government office.
  3. Clubs, racecourses and theatres were built for the ruling elites exclusively on racial grounds.
  4. Cantonment places were developed. Here Indian troops under European command were stationed. These were considered safe enclaves for Europeans.
  5. Simla, founded during the course of Gurkha war, and Darjeeling were hill stations that became strategic places for billeting troops, guarding frontiers and launching campaigns against enemy rulers.
  6. Public places such as public parks, theatres, and cinema halls came into existence for providing new forms of entertainment and social interaction.
  7. Government House Calcutta : It was built by Lord Wellesley for himself in Calcutta.

Question 8.
What were the concerns that influenced town planning in the nineteenth century?
Solution :

  1. Two concerns which influenced the town planning in the nineteenth century were defence and health.
  2. In many towns British built forts to protect their factories. Around the fort, a vast open space was left open. This vast space was known as the Maidan.
  3. It was done so that there would be no obstructions to a straight line of fire from the Fort against an advancing enemy.
  4. Attempts were also made to improve the sanitation and cleanliness by creating open spaces in the city.
  5. For this purpose, in Calcutta many bazaars, ghats and burial grounds were cleared.

Question 9.
To what extent were social relations transformed in the new cities ?
Solution :
The social relations were transformed in the new cities in the following ways :

  1. New transport facilities as horse-drawn carriages, trams and buses meant that people could live at a distance from the city centre. This led to separation of the place of work from the place of residence. People travelled from home to office or factory.
  2. The sense of coherence and familiarity of the old towns disappeared. The public places such as parks, theatres and cinema halls provided new forms of entertainment and social interaction.
  3. New social groups came into existence. The “middle classes” increased due to the coming of all types of people i.e., clerks, doctors, teachers, lawyers and others. With the spread of education, people could put forward their views in newspapers and journals. People started questioning old customs and practices.
  4. Women entered new professions as factory workers, teachers, theatres and film actresses. However, their entry into public spaces remained the objects of social censure.
  5. There was a dramatic contrast between extreme wealth and poverty. The new cities were bewildering places where life seemed always in a flux. Paupers from the villages came to cities in search of employment. The male migrants left their families in the villages because jobs were uncertain and food was expensive. But yet the villagers participated in religious festivals, tamashas and swangs which mocked the pretensions of their masters, Indian and European.

We hope the NCERT Solutions for Class 12 History Chapter 12 Colonial Cities Urbanisation, Planning and Architecture help you. If you have any query regarding NCERT Solutions for Class 12 History Chapter 12 Colonial Cities Urbanisation, Planning and Architecture, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions

NCERT Solutions for Class 12 Chemistry Chapter 2 contains solved questions asked in the textbook. The answers are provided by subject experts and hence can be used for reference. Chemistry is an important subject for boards as well as competitive exams. NCERT Solutions are therefore the best guide for the students appearing for such exams.

Every minute detail is explained in such a way that the students find it easy to understand. The students from different boards such as UP board, MP board, CBSE, Gujarat board can refer to the NCERT Solutions for Class 12 Chemistry Chapter 2 to score well in the exams.

Board CBSE
Textbook NCERT
Class Class 12
Subject Chemistry
Chapter Chapter 2
Chapter Name Solutions
Number of Questions Solved 52
Category NCERT Solutions

NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions

Class 12 Chemistry Chapter 2 Solutions are defined as homogeneous mixture of two or more components. This chapter gives an overview of different types of solutions. Various laws and its derivations are provided here stepwise for easy understanding. The NCERT Solutions for Class 12 Chapter 2 provide solutions to the questions provided in the textbook.

NCERT IN-TEXT QUESTIONS

Question 1.
Calculate the mass percent of benzene (C6H6) and carbon tetrachloride (CCl4) if 22 g of benzene is dissolved in 122 g of carbon tetrachloride.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 1

Question 2.
Calculate the mole fraction of benzene in a solution containing 30% by mass of it in carbon tetrachloride.
Answer:
Let us start with 100 g of the solution in which
Mass of benzene = 30 g
Mass of carbon tetrachloride = 70 g
Molar mass cf benzene (C6H6) = 6 x 12 + 6 x 1 = 78g mol-1.
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 2

Question 3.
Calculate the molarity of each of the following solutions:
(a) 30 g of CO(NO3)2.6H2O in 4.3 L of solution
(b) 30 mL of 0.5 M H2SO4 diluted to 500 mL.
Answer:
(a) Molar mass of CO(NO3)2.6H2O=310.7 g mol-1
no. of moles = 30/310.7 = 0.0966
Vol. of solution = 4.3 L
Molarity =0.0966/4.3 = 0.022M
(b) 1000 mL of 0.5M  H2SO4 contain H2SO4 = 0.5 mole
30 mL of 0.5 M H2SO4 contain H2SO4
=0.5/1000 x 30 = 0.015 mole
Volume of solution = 500mL=0.5 L
Molarity = 0.015/0.5 = 0.03M

Question 4.
Calculate the mass of urea (NH2CONH2) required to prepare 2-5 kg of 0-25 molal aqueous solution.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 3
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 4

Question 5.
Calculate (a) molality (b) molarity and (c) mole fraction of KI if the density of 20% (mass/mass) aqueous KI is 1.202 g mL-1.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 5
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 6

Question 6.
H2S a toxic gas with rotten egg smell, is used for the qualitative analysis. If the solubility of H2S in water at S.T.P is 0·195 m ; calculate Henry’s law constant.
Answer:
Step I. Calculation of mole fraction of H2S
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 7
Step II. Calculation of Henry’s Law constant
According to Henry’s Law,
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 8

Question 7.
Henry’s Law constant for CO2 in water is 1·67 x 108 Pa at 298 K. Calculate the quantity of CO2 in 500 mL of soda water when packed under 2·5 atm pressure of CO2 at 298 K. (D.S.B. 2008 Supp.)
Answer:
Step I. Calculation of number of moles of CO2.
According to Henry’s Law,
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 9
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 10
(\({ n }_{ { CO }_{ 2 } }\) has been neglected as the gas is very little soluble in water)
∴ \({ n }_{ { CO }_{ 2 } }\) = \({ x }_{ { CO }_{ 2 } }\) x (27·78 mol) = (1·52 x 10-3) x (27·78 mol) = 0·0422 mol
Step II. Mass of CO2 dissolved in water = (0·0422 mol) x (44 g mol-1) = 1·857 g.

Question 8.
The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 11

Question 9.
The vapour pressure of pure water at 298 K is 23·8 mm Hg. 50 g of Urea (NH2CONH2) is added to 850 g of water. Calculate the vapour pressure of water for this solution and also it’s relative lowering in vapour pressure.
Answer:
Step I. Calculation of vapour pressure of water for the solution
According to Raoult’s Law,
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 12
Step II. Calculation of relative lowering in vapour pressure
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 13

Question 10.
The boiling point of water at 750 mm Hg is 99·63°C. How much sucrose is to be added to 500 g of water so that it may boil at 100°C? (K6 for water = 0·52 K kg mol-1).
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 14

Question 11.
Calculate the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point by 1.5°C. Kf= 3.9 K kg mol-1.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 15

Question 12.
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1·0 g of a polymer of molar mass 185,000 in 450 mL of solution at 37°C.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 16

NCERT EXERCISE

Question 1.
Define the term solution. What kinds of solutions are possible? Write briefly about each type of solution with an example.
Answer:
A true solution is a homogenous mixture of two or more substances. The constituent particle which is in larger amount’’ is called a solvent and that in smaller quantity is called a solute.
TYPES OF SOLUTION
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 17

Question 2.
Give an example of a solid solution in which the solute is a gas.
Answer:
Solid in solid type. E.g: Copper in gold. This type of solutions are called alloys.

Question 3.
Define the following terms :
(i) Mole fraction
(ii) Molality
(iii) Molarity
(iv) Mass percentage.
Answer:
(i) Mole fraction :
The ratio of the number of moles of one component to the total number of moles of all the components present in the solution.
For a binary solution made up of components A and B,
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 18
(ii) Molality:
The number of gram moles of the solute dissolved in 1000 g (or kg) of the solvent.
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 19
(iii) Molarity:
The number of gram formula mass of the solute dissolved per litre of the solution.
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 20
(iv) Mass percentage:
The number of parts by mass of one component (solute or solvent) per 100 parts by mass of the solution. If A and B are the two components of a binary solution,
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 21

Question 4.
Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in an aqueous solution. What should be the molarity of such a sample of the acid if the density of the solution is 1.504 g mL-1?
Answer:
68% nitric acid by mass means that 68g mass of nitric acid is dissolved in 100g mass of solution. Molar mass of HNO3= 63g mol-1
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 22

Question 5.
A solution of glucose in water is labelled as 10 percent W/W. What would be the molality and mole fraction of each component in the solution? If the density of the solution is 1·2 g mL-1, then what should be the molarity of the solution? (C.B.S.E. 2013, Manipur Board 2015)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 23

Question 6.
How many mL of a 0·1 M HCl are required to react completely with a 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of two?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 24
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 25

Question 7.
A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. Calculate the mass percentage of the resulting solution.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 26

Question 8.
An antifreeze solution is prepared from 222·6 g of ethylene glycol C2H4(OH)2 and 200 g of water. Calculate the molality of the solution. If the density of the solution is 1·072 g mL-1, then what shall be the molarity of the solution? (C.B.S.E. Delhi 2007)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 27

Question 9.
A sample of drinking water was found to be severely contaminated with chloroform(CHCl3) supposed to be a carcinogen. The level of contamination was 15 ppm (by mass).
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in a water sample.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 30
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 31

Question 10.
What role does the molecular interaction play in a solution of alcohol and water?
Answer:
Alcohols dissolve in water due to the formation of intermolecular H-bonding with water.

Question 11.
Why do gases nearly always tend to be less soluble in liquids as the temperature is raised?
Answer:
The dissolution of a gas in a liquid is exothermic in nature because the gas contracts in volume.

Gas + Liquid ⇌ Dissolved gas ; ∆H = – ve

An increase in temperature will favour the reverse process since it is of endothermic nature. Therefore, the solubility of the gas in the solution decreases with the rise in temperature.

Question 12.
State Henry’s law and mention some important applications.
Answer:
Henry’s law: According to this law, ‘The mass of a gas dissolved per unit volume of a solvent at a constant temperature, is proportional to the pressure of the gas with which the solvent is in equilibrium’.

Let in unit volume of solvent, the mass of the gas dissolved is m and equilibrium pressure is P, then m α P or m = KP, where K is a constant. We can understand Henry’s law by taking the example of soda water bottle. Soda water contains carbon dioxide dissolved in water under pressure.

Applications of Henry’s law:

1. In the production of carbonated beverages: To increase the solubility of CO2 in soft drinks, soda water, bear etc. the bottles are sealed at high pressure.

2. In exchange of gases in the blood: The partial pressure of O2 is high in inhaled air, in lungs it combines with hemoglobin to form oxyhemoglobin. In tissues, the partial pressure of oxygen is comparatively low therefore oxyhemoglobin releases oxygen in order to carry out cellular activities.

3. In deep-sea diving: Deep-sea divers depend upon compressed air for breathing at high pressure underwater. The compressed air contains N2 in addition to O2, which are not very soluble in blood at normal pressure. However, at great depths when the diver breathes in compressed air from the supply tank, more N2 dissolved in the blood and in other body fluids because the pressure at that depth is far greater than the surface atmospheric pressure. When the divers come towards the surface at atmospheric pressure, this dissolves nitrogen bubbles out of the blood. These bubbles restrict blood flow, affect the transmission of nerve impulses. This causes a disease called bends or decompression sickness. To avoid bends, as well as toxic effects of high concentration of nitrogen in the blood, the tanks used by scuba divers are filled with air diluted with helium (11.7% He, 56.2% N2, and 32.1% O2).

4. At high altitudes: At high altitudes, the partial pressure of O2 is less than that at the ground level. This results in a low concentration of oxygen in the blood and tissues of the people living at high altitudes or climbers. The low blood oxygen causes climbers to become weak and unable to think clearly known as anoxia.

5. Aquatic life: The dissolution of oxygen (from air) in water helps in the existence of aquatic life in various water bodies like Lake, rivers, and sea.

Question 13.
The partial pressure over a saturated solution containing 6·56 x 10-2 g of ethane is 1 bar. If the solution contains 5·0 x 10-2 g of ethane, what shall be the partial pressure of the gas?
Answer:
According to Henry’s law,
The mass of the gas (m) dissolved in solution ∝ Partial pressure (p) (At constant temperature)
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 32

Question 14.
What is meant by positive and negative deviations from Raoult’s law and how is the sign of ∆Hsol related to positive and negative deviations from Raoult’s law?
Answer:
(a) Positive Deviation:
(i) ∆Vmixing is positive: This is quite likely also because in ge presence of weak forces of interaction, interaction, the volume of the solution is bound to increase.
(ii) ∆Hmixing is positive: Energy is needed to form the solution because the components of the solution have to be brought closer to form the solution. Thus, the process of mixing is of endothermic nature.
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 33
(b) Negative Deviation:

(i) ∆Vmixing is negative: Because of the increased forces of interaction, the molecules of the two components will come closer and as a result, there is a decrease in the volume of the solution.
(ii) ∆Hmixing is negative: Energy is expected to be released because of the increase in the forces of interaction. Therefore, the process of mixing is exothermic in nature or ∆Hmixing is negative.
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 34

Question 15.
An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. What is the molar mass of the solute?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 34

Question 16.
Heptane and octane form ideal solutions. At 373 K, the vapour pressure of the two liquid components is 105·2 k Pa and 46·8 k Pa respectively. If the solution contains 25 g of heptane and 35 g of octane, calculate:
(i) Vapour pressure exerted by heptane
(ii) Vapour pressure exerted by octane
(iii) Vapour pressure exerted by the solution
(iv) Mole fraction of octane in the vapour phase. (C.B.S.E. Sample Paper, 2010)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 36

Question 17.
The vapour pressure of water is 12·3 kPa at 300 K. Calculate the vapour pressure of 1 molal solution in it.
Answer:
1 molal solution implies one mole of the solute dissolved in 1000 g (1 kg) of solvent i.e. water.
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 37

Question 18.
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 38
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 40

Question 19.
A solution containing 30 g of a non-volatile solute exactly in 90 g of water has a vapour pressure of 2·8 k Pa at 298 K. Further 18 g of water is then added to the solution and the new vapour pressure becomes 2·9 k Pa at 298 K. Calculate
(i) Molecular mass of the solute.
(ii) Vapour pressure of water at 298 K. (C.B.S.E. Outside Delhi 2005)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 41
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 42
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 43

Question 20.
A 5% solution (by mass) of cane sugar in water has a freezing point of 271 K. Calculate the freezing point of a 5% glucose in water if the freezing point of pure water is 273·15 K. (C.B.S.E. Delhi 2008)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 44
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 45
Freezing point temperature of glucose solution = (273·15 – 4·085) K = 269·07 K.

Question 21.
Two elements A and B form compounds having molecular formulae AB2 and AB4. When dissolved in 20 g of benzene, 1 g of AB2 lowers the freezing point by 2·3 K whereas 1 g of AB4 lowers it by 1·3 K. Molal depression constant for benzene is 5·1 K kg mol-1. Calculate atomic masses of A and B. (C.B.S.E. Delhi 2004)
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 46
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 47

Question 22.
At 300 K, 36g of glucose present in a litre of its solution has an osmotic pressure of 4.08 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 48

Question 23.
Suggest the most important type of intermolecular attractive interactions in the following pairs :

  1. n-hexane and n-octane
  2. I2 and CCl4
  3. NaClO4 and water (H2O)
  4. methanol and acetone
  5. acetonitrile (CH3CN) and acetone (C3H6O).

Answer:

  1. Both are non-polar. Hence, intermolecular interactions in them will be London/ dispersion forces (discussed in class XI)
  2. Both are non-polar. Hence, intermolecular interactions in them will be London/ dispersion forces (discussed in class XI)
  3. NaClO4 gives Na+ and ClO4 ions in the solution while water is a polar molecule. Hence, intermolecular interactions in them will be ion-dipole interactions.
  4. Both are polar molecules. Hence intermolecular interactions in them will be dipole-dipole interactions.
  5. Both are polar molecules. Hence intermolecular interactions in them will be dipole-dipole interactions.

Question 24.
Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain.
Cyclohexane, KCl, CH3OH, CH3CN.
Answer:
(i) Cyclohexane and n-octane both are non-polar. Hence they mix completely in all proportions.
(ii) KCl is an ionic compound while n-octane is nonpolar. Hence, KCl will not dissolve at all in n-octane.
(iii) CH3OH and CH3CN both are polar but CH3CN is less polar than CH3OH. As the solvent is non-polar, CH3CN will dissolve more than CH3OH is n-octane.
Thus the order of solubility will be KCl< CH3OH < CH3CN < Cyclohexane.

Question 25.
Among the following compounds, identify which are insoluble, partially soluble, and highly soluble in water?
(i) phenol
(ii) toluene
(iii) formic acid
(iv) ethylene glycol
(v) chloroform
(vi) pentanol.
Answer:
(i) phenol (C6H5OH): Is partially soluble in water due to weak dipole-dipole interactions in the molecules of phenol and water.
(ii) toluene (C7H8): Is insoluble in water because it is an aromatic hydrocarbon (non-polar) while water is polar in nature.
(iii) formic acid (HCOOH): Is highly soluble in water since it can form hydrogen bonding with water.
(iv) ethylene glycol (HOCH2CH2OH): Is highly soluble in water since it can form hydrogen bonding with water.
(v) chloroform (CHCl3): Is insoluble in water because it is an organic heavy liquid and forms a separate layer.
(vi) pentanol (C5H11OH): In partially soluble in water because the bulky C5H11 group decreases its extent of hydrogen bonding with water.

Question 26.
If the density of some lake water is 1.25 g mL-1 and contains 92g of Na+ ions per kg of water, calculate the molality of Na+ ions in the lake.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 49

Question 27.
If the solubility product of CuS is 6 x 10-16, calculate the maximum molarity of CuS in aqueous solution.
Answer:
Dissociation of CuS in aqueous solution is :
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 50
By definition, Ksp corresponds to the product of the ionic concentration of the salt in saturated solution and it represents the maximum molarity of the salt. Therefore, maximum molarity of the salt = 2· 45 x 10-8 M.

Question 28.
Calculate the mass percent of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6·5 g of aspirin is dissolved in 450 g of CH3CN.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 51

Question 29.
Nalorphene (C19H21NO3) similar to morphine is used to combat withdrawal symptoms in narcotic users. Dose of nalorphene generally given is 1· 5 mg. Calculate the mass of 1· 5 x 10-3 m aqueous solution required for the above doze?
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 52

Question 30.
Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution in methanol 0.15 M solution means that 0.15 mole of benzoic acid is dissolved in 1L of solution.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions image - 1
Question 31.
The depression in freezing point of water observed for the same amount of acetic acid, trichloroactetic acid and trifluoroacetic acid increases in the order given above. Explain. (C.B.S.E. 2008 Supp.)
Answer:
The depression in freezing point of a solute in water depends upon the number of particles or ions furnished by it in solution or upon its degree of dissociation (α). All the three organic acids ionise in aqueous solution. However, the relative order of acidic strengths is as given below.
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 53

This is linked with the electronegativity of the halogen atoms present. Fluorine (F) is more electronegative than (Cl). Under the circumstances, trifluoroacetic acid gives maximum ions in solution since it is the strongest acid. Consequently, the depression in freezing point (∆Tf) is the maximum in this case and is the least for acetic acid which is the weakest acid.

Question 32.
Calculate the depression in the freezing point of water when 10 g of CH3CH2CH(Cl)COOH is added to 250 g of water. Ka = 1·4 x 10-3; Kf = 1·86 K kg mol-1. (C.B.S.E. 2008 Supp.)
Answer:
Step I. Calculation of degree of dissociation of acid Mass of acid = 10 g
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 54
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 55

Question 33.
19·5 g of CH3FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed is 1·0°C. Calculate Van’t Hoff factor and dissociation constant of the acid: Kf = 1·86 K kg mol-1.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 56

Question 36.
100 g of liquid A (molar mass 140 g mol-1) was dissolved in 1000 g of liquid B (molar mass 180 g mol-1). The vapour pressure of pure liquid B was found to be 500 torrs. Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 torr.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 58

Question 37.
Vapour pressures of pure acetone and chloroform at 328 K are 632·8 mm Hg and 741·8 mm Hg respectively. Assuming that they form an ideal solution over die entire range of composition, plot ptotal. pchloroform, and pacetone as a function of xacetone. The experimental data observed for different compositions of the mixture is:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 59
Plot this data also on the same graph paper. Indicate whether it has positive deviation or negative the ideal solution.
Answer:
From the available information:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 60
Since the plot or graph dips downwards, the solution shows a negative deviation from Raoult’s Law.

Question 38.
Benzene and naphthalene form ideal solutions over the entire range of composition. The vapour pressure of pure benzene and naphthalene at 300 K are 50·71 mm Hg and 32·06 mm Hg respectively. Calculate the mole pure fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of naphthalene.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 61

Question 39.
Air is a mixture of a number of gases. The major components are oxygen and nitrogen with the approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K if Henry’s law constants for oxygen and nitrogen at 298 K are 3·30 x 107 mm and 6·51 x 107 mm respectively, calculate the composition of these gases in water.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 62

Question 40.
Determine the amount of CaCl2 (i = 2·47) dissolved in 2·5 litre of water so that its osmotic pressure is 0·75 atm at 27°C.
Answer:
According to Van’t Hoff equation :
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions 63

Question 41.
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 litre of water at 25°C, assuming that it is completely dissociated.
Answer:
NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions image - 3
We hope the NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions help you. If you have any query regarding NCERT Solutions for Class 12 Chemistry Chapter 2 Solutions, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry

NCERT Solutions for Class 12 Chemistry Chapter 5 are the practice guide for all the students. It contains solved questions provided by the subject matter experts. The solutions are accurate and the answers can be written in the exams.

NCERT Solutions are provided for reference in various boards (CBSE, UP board, Gujarat board, MP board). These help the students practice well before the examination and know their shortcomings. NCERT Solutions not only help the students score well in the board exams but also help them get through competitive exams.

Board CBSE
Textbook NCERT
Class Class 12
Subject Chemistry
Chapter Chapter 5
Chapter Name Surface Chemistry
Number of Questions Solved 35
Category NCERT Solutions

NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry

Class 12 Chemistry Chapter 5 Surface Chemistry is an important chapter and explains the types of chemical reactions, its pocesses and mechanisms that take place at the surface of the material. The chapter also contains the details on various important concepts such as Tyndall effect, Brownian motion, and catalyst reactions. Notes on various topics like colloids, emulsions, electrodialysis, enzyme reactions, electrophoresis, etc. are also provided here for reference.

NCERT IN-TEXT QUESTIONS

Question 1.
Why are substances like platinum and palladium often used for carrying out the electrolysis of aqueous solutions ?
Answer:
The metals like platinum and palladium are used as inert electrodes for carrying out the process of electrolysis because these are not attacked by the ions involved in the process.

Question 2.
Why does physisorption decrease with increase in temperature ?
Answer:
Physisorption or physical adsorption of a gas on the surface of a solid is exothermic in nature.
NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry 1
When temperature is increased, the equilibrium gets shifted in the backward direction to neutralise the effect of increase in temperature. Consequently, physisorption decreases with the increase in temperature.

Question 3.
Why are powdered substances more effective . adsorbents than their crystalline forms?
Answer:
Powdered substances have greater surface area as compared to their crystalline forms. Greater the surface area, greater is the adsorption.

Question 4.
Why is it necessary to remove CO when ammonia is obtained by Haber’s process ?
Answer:
Carbon monoxide (CO) acts as a poison for the catalyst iron as well as promoter molybdenum which are used in the Haber’s process. Moreover, it is likely to combine with iron to form iron carbonyl Fe(CO)5. Therefore, it is necessary to remove it from the reaction mixture by suitable means.

Question 5.
Why is ester hydrolysis slow in the beginning and becomes fast after sometime ?
Answer:
In ester hydrolysis, an acid and alcohol are formed as the products. For example,
NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry 2
Acid will release H+ ions in solution which act as catalyst (auto-catalysis) for the reaction. That is why, the hydrolysis is slow in the beginning and becomes faster later on.

Question 6.
What is the role of desorption in the process of catalysis?
Answer:
Desorption makes the surface of the solid- catalyst-free for fresh adsorption of the reactants on the surface.

Question 7.
What modification can you suggest for Hardy-Schulze Law?
Answer:
According to Hardy-Schulze Law, the ions carrying charge opposite to the charge on sol particles neutralise their charge and thus cause their coagulation or precipitation. The law takes into account the charge carried by the ion and not its size. Smaller the size of the ion more will be its polarising power. Thus, the law should be modified in terms of the polarising power of the flocculating ion or the ion causing the precipitation. The modified form of the law states that “Greater the polarising power of the flocculating ion added, greater is its power to cause precipitation.”

Question 8.
Why is it essential to wash the precipitate with water before estimating it quantitatively?
Answer:
Some amounts of the electrolyte are mixed to form the ppt. Some of these electrolytes remain adsorbed on the surface of the particles of the ppt. Hence, it is essential to wash the ppt with water to remove the sticking electrolytes (or any other impurities) before estimating it quantitatively.

NCERT EXERCISE

Question 1.
Distinguish between the meaning of terms adsorption and absorption. Give one example in each case.
Answer:
Differences between Adsorption and Absorption:

Adsorption:

  1. It is a process as a result of which one substance gets concentrated only on the surface of the other.
  2. The concentration of adsorbate on the surface of the adsorbent is different than in the bulk.
  3. It is a surface phenomenon.
  4. Example: Adsorption of water vapour on silica gel.

Absorption:

  1. It is a process as a result of which one substance gets uniformly distributed in the volume of the other.
  2. Concentration is uniform in the entire solid system.
  3. It is a bulk phenomenon.
  4. Example: Adsorption of water vapour by dry calcium chloride.

Question 2.
What is the difference between physisorption and chemisorption?

Answer:
NCERT Solutions For Class 12 Chemistry Chapter 5 Surface Chemistry-3

Question 3.
Why is a finely divided substance more effective as an adsorbent ?
Answer:
With the increase in surface area of adsorbent adsorption increases. Thus, in the powdered state (finely divided substance) or in porous state surface area of metals is more. Therefore, adsorption is more in these states.

Question 4.
What are the factors which influence the adsorption of a gas on a solid ?
Answer:
There are various factors that affect the rate of adsorption of a gas on a solid surface.

  • Nature of the gas: Easily liquefiable gases such as NH3, HCl, etc. are adsorbed to a great extent in comparison to gases such as H2, O2, etc. This is because Van der Waal’s forces are stronger in easily liquefiable gases.
  • The surface area of the solid: The greater the surface area of the adsorbent, the greater is the adsorption of a gas on the solid surface.
  • Effect of pressure: Adsorption is a reversible process and is accompanied by a decrease in pressure. Therefore adsorption increases with an increase in pressure.
  • Effect of temperature: Adsorption is an exothermic process. Thus in accordance with Leehatelie’s principle, the magnitude of adsorption decreases with an increase in temperature.

Question 5.
What is adsorption isotherm ? Distinguish between Freundlich adsorption isotherm and Langmuir adsorption isotherm.
Answer:
Adsorption isotherm represents the variation of the amount of the gas adsorbed and the corresponding pressure at a certain temperature. The mathematical forms of the two adsorption isotherms are :
vedantu class 12 chemistry Chapter 5 Surface Chemistry 3
The main points of distinction in the two adsorption isotherms are:

  • Freundlich Adsorption isotherm is applicable to all types of adsorption whereas Langmuir Adsorption isotherm is applicable mainly to chemical adsorption or chemisorption.
  • Freundlich adsorption isotherm fails at high pressure of the gas whereas Langmuir Adsorption isotherm can be applied under all pressures.

Question 6.
What do you understand by activation of adsorbent? How is it achieved?
Answer:
By activating an absorbent, we tend to increase the adsorbing power of the adsorbent. Some ways to activate an adsorbent are:

  1. By increasing the surface area of the adsorbent. This can be done by breaking it into smaller pieces or powdering it.
  2. Some specific treatments can also lead to the activation of the adsorbent.

For example, wood charcoal is activated by heating it between 650K and 1330K in vacuum pr air. It expels all the gases absorbed or adsorbed and thus, creates a space for the adsorption of gases.

Question 7.
What role does adsorption play in heterogeneous catalysis?
Answer:
Heterogeneous catalysis is generally carried on the surface of the finely divided metals of the transition series. Due to the availability of large surface area, the reacting species get adsorbed on the surface either by physical adsorption or by chemisorption. The adsorbed species get opportunity to mutually combine to form the products which are released or desorbed from the surface so as to accommodate more reacting species.
vedantu class 12 chemistry Chapter 5 Surface Chemistry 4

  • Diffusion of the reactants on the surface of the catalyst.
  • Some association between the catalyst surface and the reactants i. e., adsorption.
  • The occurrence of the chemical reactions on the catalyst surface.
  • Dissociation of the reaction products from the catalyst surface i.e., desorption.
  • Diffusion of the products from the catalyst surface.

Question 8.
Give two chemical methods for the preparation of colloids.
Answer:
These are formed in two ways:

  • Condensation methods
  • Dispersion methods.

Condensation methods: The particles of the dispersed phase are very small in size. They have to be condensed suitably to be of colloidal size.
A colloidal solution of sulphur is obtained when H2S gas is bubbled through the solution of oxidising agent like bromine water, sulphur dioxide, dilute HNO3 etc.
Dispersion methods: In these methods, bigger particles of a substance (suspension) are broken into smaller particles of colloidal dimensions. The substance whose colloidal solution is to be prepared, is first ground to coarse particles. It is then mixed with the dispersion medium to get a suspension

Question 9.
How are colloidal solutions classified on the basis of physical states of the dispersed phase and dispersion medium?
Answer:
There are in all eight types of colloidal solutions.
vedantu class 12 chemistry Chapter 5 Surface Chemistry 5

Question 10.
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Answer:
Effect of pressure:
Adsorption is a reversible process and is accompanied by a decrease in pressure. Therefore adsorption increases with an increase in pressure.

Effect of temperature:
Adsorption is an exothermic process. Thus, in accordance with Le-chatelier’s principle, the magnitude of adsorption decreases with an increase in temperature.

Question 11.
What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?
Answer:
Lyophillic colloids (solvent loving) are those substances that directly pass into the colloidal state when brought- in contact with the solvent, e.g., proteins, starch, rubber, etc.
These sols are quite stable because of the strong attractive forces between the particles of disperse phase and the dispersion medium.
Lyophobic colloids (solvent hating) are those substances that do not form the colloidal sol readily when mixed with the dispersion medium.These sols are less stable than the lyophilic sols. Examples of lyophobic sols include sols of metals and their insoluble compounds like sulphides and hydroxides.
The stability of hydrophobic sol is only due to the presence of charge on the colloidal parties. If charge is removed, e.g., by addition of suitable electrolytes, the particles will come nearer to each other to form aggregate, i.e., they will coagulate and settle down. On the other hand, the stability of hydrophilic sol is due to charge as well as solvation of the colloidal particles. Thuf, for coagulation to occur easily both the mentioned factors have to be removed.

Question 12.
What is the difference between muitimolecular and macromolecular colloids ? Give one example of each. How are associated colloids different from these two types of colloids ? (C.B.S.E. 2008, 2009, 2010)
Answer:
Difference between multimolecular and macromolecular colloids
The main points of distinction are listed.

Muitimolecular colloids Macromolecular colloids

1.The particle size is less than that of the colloidal range (< 103 pm)
2. They exist as aggregates of smaller particles.
3. These are mostly lyophobic colloids.

1. The particle size falls in the colloidal range (103 to 106 pm).
2. These are already macro molecular in nature.
3. These are mostly lyophilic colloids.

Colloidal sol of sulphur (Sg) is an example of multimolecular colloid while colloidal sol of starch represents macromolecular colloid.

Associated colloids also called micelles, are generally electrolytes. They exist as ions at low concentrations. However, above a particular concentration called critical micellear concentration (CMC) and above a particular temperature called Kraft temperature (Tk), these get associated and exhibit colloidal behaviour. Soap is a common example of associated colloids.

Multimolecular colloids: In these colloids, the individual particles consist of an aggregate of atoms or small molecules with molecular size less than 103 pm. For example, gold sol consists of particles of various sizes having several atoms. Similarly, a sulphur sol consists of particles each having eight sulphur atoms (Sg). In these colloids, the particles are held by van der Waals’ forces.

Macromolecular colloids: In this type, the particles of the dispersed phase are sufficiently big in size (macro) to be of colloidal dimensions. These are normally polymers. A few naturally occurring macromolecules are starch, cellulose and proteins. The examples of artificial macromolecules are those of polythene, nylon, polystyrene, plastics etc.

Question 13.
What are enzymes? Write in brief the mechanism of enzyme catalysis.
Answer:
Enzymes are complex nitrogenous compounds which are produced by living plants and animals. In fact, these are proteins produced by living systems and catalyse certain biological reactions. These are, therefore, often known as bio-chemical catalysts and this phenomenon is known as bio-chemical catalysis.
NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry 6
The rate of enzyme-catalyzed reaction which is initially of first-order changes to zero-order as the concentration of substrate species on the catalyst surface increases.
Two models have been proposed by bio-chemists to explain the mechanism of enzyme catalyzed reactions. These are briefly discussed.

Question 14.
How are colloids classified on the basis of :
(a) physical states of components
(b) nature of dispersion medium
(c) interaction between the dispersed phase and dispersion medium?
Answer:
(a) Based on physical states of components. Based on the physical states of components i.e., dispersed phase and dispersion medium, there are eight types of colloidal solutions.
NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry 7
(b) Nature of dispersion medium. The dispersion medium can be either gas, liquid or solid. Based upon its nature, the colloids or colloidal solutions are of three types.

  • Aerosols: Air or gases act as the dispersion medium
  • Liquid sols: Liquids like water, alcohol or benzene act as the dispersion medium.
  • Solid sols: Solid acts as the dispersion medium.

(c) Interaction between the dispersed phase and dispersion medium. Colloidal solutions are classified into two types. These are lyophilic and lyophobic sols.
(i) Lyophilic colloids: The colloidal solution in which the particles of the dispersed phase have a great affinity (or love) for the dispersion medium, are called lyophilic colloids. Such solutions are easily formed the moment the dispersed phase and the dispersion medium come in direct contact. e.g., sols of gum, gelatin, starch, etc.

(ii) Lyophobic colloids: The colloidal solutions in which the particles of the dispersed phase have no affinity or love, rather have hatred for the dispersion medium, are called lyophobic colloids. The solutions of metals like Ag and Au, hydroxides like Al(OH)3 and Fe(OH)3 and metal sulphides like As2S3 are examples of lyophobic colloids.

Question 15.
Explain what is observed
(i) when a beam of light is passed through a colloidal sol.
(ii) an electrolyte, NaCI is added to hydrated ferric oxide sol.
(iii) electric current is passed through a colloidal sol.
Answer:
(i) Scattering of light by colloidal particles takes place and the path of the light becomes visible (Tyndall effect).
(ii) The positively charged colloidal particles of Fe(OH)3 get coagulated by the oppositely charged Cl ions provided by NaCl.
(iii) On passing electric current, the colloidal particles move towards the oppositely charged electrode where they lose their charge and get coagulated. This is the electrophoresis process.

Question 16.
What are emulsions? What are their different types? Give an example of each type.
Answer:
(a) Oil-in-water emulsion (O/W type). In this case, the dispersed phase is oil while the dispersion medium is water. Milk is a common example in which liquid fats are dispersed in water. Similarly, if a few drops of nitrobenzene (oil) is added to water, an emulsion results. Vanishing cream is another example of this type.

(b) Water-in-oil emulsion (W/O type). In this type of emulsions, the dispersed phase is water while the dispersion medium is oil. Butter is an example of water in oil emulsion in which water is dispersed in oil. Cod liver oil and cold cream are the other examples of these emulsions.
NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry 8

Question 17.
What is demulsification? Name two demulsifiers.
Answer:
The process of separation of constituent liquids of an emulsion is called demulsification. Demulsification can be done by centrifuging or boiling.

Question 18.
The action of soap is due to demulsification and micelle formation. Comment.
Answer:
Soap is sodium or potassium salt of a higher fatty acid and may be represented as RCOO Na+ (e.g., sodium stearate CH3(CH2)]16 COO Na+, which is a major component of many bar soaps). When dissolved in water, it dissociates into RCOO and Na+ ions. The RCOO ions, however, consist of two parts – a long hydrocarbon chain R (also called non-polar tail’) which is hydrophobic (water-repelling), and a polar group COO (also called polar ionichead’), which is hydrophilic (water loving).

The RCOO ions are, therefore, present on the surface with their COO groups in water and the hydrocarbon chains R staying away from it and remain at the surface. But at critical micelle concentration, the anions are pulled into the bulk of the solution and aggregate to form a spherical shape with their hydrocarbon chains pointing towards the centre of the sphere with COO part remaining outward on the surface of the sphere. An aggregate thus formed is known as ‘ionic micelle’.

The cleansing action of soap is due to the fact that soap molecules form micelle around the oil droplet in such a way that the hydrophobic part of the stearate ions is in the oil droplet and the hydrophilic part projects out of the grease droplet like the bristles
NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry 9

Question 19.
Give four examples of heterogeneous catalysts.
Answer:
(i) The combination between nitrogen and hydrogen to form ammonia in the presence of finely divided iron acting as catalyst. This is known as Haber’s process.
vedantu class 12 chemistry Chapter 5 Surface Chemistry 10
(ii) Formation of sulphur trioxide by the oxidation of sulphur dioxide in the presence of platinum catalyst is the basis of the manufacture of sulphuric acid in Contact process.
vedantu class 12 chemistry Chapter 5 Surface Chemistry 11
(iii) Oxidation of ammonia into nitric oxide in the presence of platinum catalyst is employed for the commercial preparation of nitric acid in Ostwald process.
vedantu class 12 chemistry Chapter 5 Surface Chemistry 12
(iv) In the hydrogenation of vegetable oils (unsaturated in nature) resulting in solid fats (saturated in nature), hydrogen gas is passed through the oil in the presence of nickel catalyst at about 473 K.
vedantu class 12 chemistry Chapter 5 Surface Chemistry 13

Question 20.
What do you mean by activity and selectivity of catalysts?
Answer:
(a) Activity: The activity of a catalyst depends upon the strength of chemisorption to a large extent. The reactants must get adsorbed reasonably strongly onto the catalyst to become active. But adsorption must not be so strong that they are immobilised. It is observed that maximum activity is shown by elements of groups 7 – 9 of the periodic table
2H2 + O2 \(\underrightarrow { Pt }\) 2H2O

(b) Selectivity: The selectivity of a catalyst is its ability to yield a particular product in the reaction e.g.,
NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry 14
Thus, a selective catalyst can act as a catalyst in one reaction and may fail to catalyze another reaction.

Question 21.
Describe some features of catalysis by zeolites.
Answer:

  1. Zeolites are hydrated alumino-silicates. They have a three-dimensional network structure. They contain water molecules in their pores,
  2. Zeolites are heated to remove the water from hydration. The pores become vacant and zeolites are ready to act as catalysts.
  3. The size of the pores varies from 260 pm to 760 pm. This shows that only those molecules can be adsorbed in these pores whose size is small enough to enter these pores. Thus, zeolites a molecular sieve and the shape-selective catalysts.

Question 22.
What are shape-selective catalysts?
Answer:
The catalytic reaction that depends upon the pore structure of the catalyst and the size of the reactant and product molecules is called shape-selective catalysis. Zeolites are good shape-selective catalysts because of their honeycomb-like structures. They are microporous aluminosilicates with a three-dimensional network of silicates in which some silicon atoms are replaced by aluminium atoms giving an Al-O-Si framework. The reactions taking place in zeolites depend upon the size and shape of reactant and product molecules as well as upon the pores and cavities of the zeolites. They are found in nature as well as synthesized for catalytic selectivity.

Question 23.
Explain the following terms:
(i) Electrophoresis
(ii) Coagulation
(iii) Dialysis
(iv) Tyndall effect.
Answer:
(i) Electrophoresis:
The movement of colloidal particles under the influence of an electric field is known as electrophoresis. Positively charged particles move to the cathode, while negatively charged particles move towards the anode. As the particles reach oppositely charged electrodes, they become neutral and get coagulated.

(ii) Coagulation:
The process of setting down colloidal particles i.e., conversion of a colloid into a precipitate is called coagulation.

(iii) Dialysis: The process of removing dissolved substances from a colloidal solution by the means of diffusion through a membrane is known as dialysis. This process is based on the principle that ions and small molecules can pass through animal membranes, unlike colloidal particles.

(iv) Tyndall effect:
When a beam of light is allowed to pass through a colloidal solution, it becomes visible like a column of light. This is known as the Tyndall effect. This phenomenon takes place as particles of colloidal dimension scatter light in all directions.

Question 24.
Give four uses of emulsions.
Answer:
Four uses of emulsions:

  1. the cleansing action of soaps is based on the formation of emulsions
  2. digestion of fats in the intestines takes place by the process of emulsification.
  3. Antiseptics and disinfectants when added to water form emulsions.
  4. The process of emulsification is used to make medicines.

Question 25.
What are micelles? Give an example of the micelles system.
Answer:
Micelles are substances that behave as normal strong electrolytes at low concentration but at high concentrations behave as colloids due to the formation of aggregates. They are also called associated colloids, e.g., soaps and detergents. They can form ions and may contain 100 or more molecules to form a micelle.

Question 26.
Explain the terms with suitable examples:

  1. Alcosol
  2. Aerosol
  3. Hydrosol.

Answer:

  1. Alcosol: It is a colloidal solution in which alcohol is the dispersion medium. For example, colloids which has cellulose nitrate as a dispersed phase and ethyl alcohol as the dispersion medium.
  2. Aerosol: It is a colloidal solution in which liquid is a dispersed phase and gas is a dispersion medium e.g., fog, mist, cloud, etc.
  3. Hydrosol: It is a colloidal solution in which solid is a dispersed phase and water is a dispersion, e.g., gold sol, arsenious sulphide sol, ferric oxide sol, etc.

Question 27.
Comment on the statement that colloid is not a substance but a state of substance’.
Answer:
Common salt (atypical crystalloid in an aqueous medium) behaves as a colloid in a benzene medium. Hence, we can say that a colloidal substance does not represent a separate class of substances. When the size of the solute particle lies between 1 nm and 1000 nm, it behaves as a colloid.

Hence, we can say that colloid is not a substance but a state of the substance which is dependent on the size of the particle.
A colloidal state is intermediate between a true solution and a suspension.

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NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics

NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics

NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics are part of NCERT Solutions for Class 12 Physics. Here we have given. NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics

Board CBSE
Textbook NCERT
Class Class 12
Subject Physics
Chapter Chapter 10
Chapter Name Wave Optics
Number of Questions Solved 21
Category NCERT Solutions

Question 1.
Monochromatic light of wavelength 589 nm is incident from air on a water surface. What are the wavelength, frequency and speed of
(a) reflected, and
(b) refracted light ? Refractive index of water is 1.33. (C.B.S.E. Sample Paper 1991)
Answer:
(a) For reflected light wavelength is unchanged i. e.
X = 589 x 10-9 m = 589 nm
Also, speed of light in air c = 3 x 108 m s -1
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 1
Question 2.
What is the shape of the wavefront in each of the following cases:
(a) Light diverging from a point source.
(b) Light emerging out of a convex lens when a point source is placed at its focus.
(c) The portion of the wavefront of light from a distant star intercepted by the Earth.
Answer:
(a) Spherical shape
(b) Plane wavefront
(c) Plane wavefront

Question 3.
(a) The refractive index of glass is 1.5. What is the speed of light in glass? (Speed of light in a vacuum is 3.0 x 108 m s-1)
(b) Is the speed of light in glass independent of the colour of light? If not, which of the two colours red and violet travels slower in a glass prism ?
Answer:
(a)
Here ,n=105,c=3.0 x 108 ms-1
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 2
speed of light when passing through glass depends on colour of light. λr > λυ , therefore the speed of violet light is less than the red light.

Question 4.
In a Young’s double-slit experiment, the slits are separated by 0.28 mm and the screen is placed 1.4 m away. The distance between the central bright fringe and the fourth bright fringe is measured to be 1.2 Determine the wavelength of light used in the experiment.
Answer:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 3

Question 5.
In Young’s double-slit experiment using monochromatic light of wavelength λ, the intensity of light at a point on the screen where path difference is λ is K units. What is the intensity of light at a point where path difference is λ/2 ?
Answer:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 4

Question 6.
A beam of light consisting of two wavelengths 650 nm and 520 nm is used to obtain interference fringes in a Young’s double-slit experiment.
(a) Find the distance of the third bright fringe on the screen from the central maximum for wavelength 650 nm.
(b) What is the least distance from the central maximum where the bright fringes due to both the wavelengths coincide ?
The distance between two slits is 2 mm and distance between the plane of the slits and the screen is 1.2 m.
Answer:
(a) λ = 650 nm = 650 x 10-9 m,
d = 2 mm = 2 x 10-3 m,
D = 1.2 m
Distance of mth bright fringe from the central maximum is given by
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 5

Question 7.
In a double-slit experiment, the angular width of a fringe is found to be 0.2° on a screen placed 1 m away. The wavelength of light used is 600 nm. What will be the angular width of the fringe if the entire experiment apparatus is immersed in water ? Take
refractive index of water to be \(\frac { 4 }{ 3 } \)
Answer:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 6

Question 8.

What is the Brewster angle for air to glass transition? (Refractive index of glass = 1.5.)
Answer:
µ = 1.5
According to Brewster’s law,
µ = tan p
tan p = 1.5
⇒ p = 56.31º

Question 9.
Light of wavelength 5000 A falls on a plane reflecting surface. What are the wavelength and frequency of the reflected light ? For what angle of incidence is the reflected ray normal to the incident ray ?
Answer:
Here X = 5000 A = 5000 X 10-10 m,
c =3 x 108 m s-1
Wave length of reflected light
= Wavelength of incident light = 5000 Å
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 7

Question 10.

Estimate the distance for which ray optics is good approximation  for an aperture  of
4 mm and wavelength 400 nm.
Answer:
Here X = 400 nm = 400 x 10-9 m, Aperture, a = 4 mm = 4 x 10-3 m
.’. Distance for which  ray optics is a good approximation is Fresnel’s distance
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 8

Question 11.

The 6563 Å Hα line emitted by hydrogen in a star is found to be red-shifted by 15Å. Estimate the speed with which the star is receding from the Earth.
Answer:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 9

Negative sign shows that the star is receding away from the earth.

Question 12.
Explain how Corpuscular theory predicts the speed of light in a medium, say, water, to be greater than the speed of light in vacuum. Is the prediction confirmed by experimental determination of the speed of light in water ? If not, which alternative picture of light is consistent with experiment ?
Answer:
According to Corpuscular theory, when light in the form of particles enters into denser medium from a rarer medium, a force of attraction comes into play on the particles normal to the surface. Thus, the component of velocity normal to the surface of water increases whereas the component of velocity parallel to surface does not change. Therefore,
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 10
velocity in water is greater than velocity of light in air. However, in actual case, c > υ. Huygen’s wave theory of light is consistent with the experiment.

Question 13.
You have learnt in the text how Huygens’ principle leads to the laws of reflection and refraction. Use the same principle to deduce directly that a point object placed in front of a plane mirror produces a virtual image whose distance from the mirror is equal to the object distance from the mirror.
Answer:
Let there be a point object A at a distance y from a plane mirror. Treating this point to be a point source of light, we can assume spherical wavefronts progressing from A of radius y. Let there be no mirror then after time t, the wavefront will reach A’ as wavefront I. If a mirror is placed as shown in the figure then image will be formed at A’ represented by II.
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 11
It is seen that OA’ = OA i. e. virtual image is formed at a distance equal to the distance of object from the mirror.

Question 14.
Let us list some of the factors, which could possibly influence the speed of wave propagation:
(1) nature of the source,
(2) direction of propagation.
(3) the motion of the source and/or observer.
(4) wavelength
(5) intensity of the wave.
On which of these factors, if any, does
(a) the speed of light in vacuum,
(b) the speed of light in a medium (say, glass or water), depend ?
Answer:
(a) Speed of light in a vacuum is an absolute constant (universal constant). It is independent of any factor. It is independent of the relative motion between source and observer even.
(b)

  1. Speed of light in a medium depends upon wavelength.
  2. It is independent of the nature of the source and motion of the source relative to the medium.
  3. It depends upon the properties of the medium of propagation and motion of the observer relative to the medium,
  4. It is independent of the direction of propagation for isotropic medium,
  5. It is independent of the intensity of the wave.

Question 15.
For sound waves, the Doppler formula for frequency shift differs slightly between the two situations :
(1) a source at rest; observer moving, and
(2) source moving ; observer at rest. The exact Doppler formulae for the case of light waves in vacuum are, however, strictly identical for these situations. Explain why this should be so. Would you expect the formulae to be strictly identical for the two situations in case of light travelling in a medium ?
Answer:
Sound requires material medium for propagation. Though situations
(1) and (2) may correspond to the same relative motion, yet they are not identical physically as the motion of observer relative to medium may be different in both situations. Hence, Doppler effect for sound cannot be same in both situations. Light when passing through material medium is also governed by different Doppler formulae for
(1) a source at rest; observer moving and
(2) source moving; observer at rest.
But when light passes through vacuum the formulae become exactly same for the two different situations because speed of light and frequency/wavelength of light remain unchanged in vacuum.

Question 16.
In a double-slit experiment using light of wavelength 600 nm, the angular width of a fringe formed on a distant screen is 0.1°. What is the spacing between two slits?
Answer:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 12

Question 17.
Answer the following questions :
(a)
In a single-slit diffraction experiment, the width of the slit is made double the original width. How does this affect the size and intensity of the central diffraction
band ?
(b) In what way is diffraction from each slit related to the interference pattern in a double-slit experiment? (C.B.S.E. 2013, 2013 )
(c)
When a tiny circular obstacle is placed in the path of light from a distant source, a bright spot is seen at the center of the shadow of the obstacle.
Explain why? (C. B. S. E. 2013 )
(d)
Two students are separated by a 7 m partition wall in a room 10 m high. If both light and sound waves can bend around obstacles, how is it that the students are unable to see each other even though they can converse easily ?   (C.B.S.E. 1990 )
(e)
Ray optics is based on the assumption that light travels in a straight line. Diffraction effects (observed when light propagates through small apertures/slits or around small obstacles) disprove this assumption. Yet the ray optics assumption is so commonly used in understanding location and several other properties of images in optical instruments. What is the justification?   (C.B.S.E. 1990)
Answer:
(a) The width of central maxima = 2λD/d.
When the width (d) of slit is doubled, then the width of central diffraction maxima reduces to half and the intensity of the central band increases four times as amplitude of light wave is doubled.
(b) Intensity of fringes produced in the double-slit experiment is changed due to diffraction pattern superposing due to each slit.
(c) Light waves diffract at the edges of the circular obstacle. These diffracted waves interfere constructively and give rise to the bright spot at the center of the geometrical shadow.
(d) Diffraction is observed when the wavelength of the wave is of the order of the size of the obstacle. The wavelength of sound wave (≈ 0.33 m) is larger than the light wave (≈10-7 m) and is also comparable to wall, so diffraction of sound waves takes place and hence the students can converse easily. On the other hand, the wavelength of light is very small as compared to the obstacle e. 1 m high wall so the diffraction of light waves does not take place.
(e) In optical instruments, size of apertures are much larger than the wavelength of light. So diffraction of light is negligible. Hence, the assumption that light can travel in straight line is used in optical instruments.

Question 18.
Two towers on top of two hills are 40 km apart. The line joining them passes 50 m above a hill halfway between the towers. What is the longest wavelength of radio waves, which can be sent between the towers without appreciable diffraction effects ?
Answer:
If A and B are two hills and C is the hill peak midway
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 13
Question 19.
A parallel beam of light of wavelength 500 nm falls on a narrow slit and the resulting diffraction pattern is observed on a screen 1 m away. It is observed that the first minimum is at a distance of 2-5 mm from the center of the screen. Find the width of the slit.( C.B.S.E. 2013)
Answer:

NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 14

Question 20.
Answer the following questions :
(a) When a low flying aircraft passes overhead, we sometimes notice a slight shaking of the picture on our TY screen. Suggest a possible explanation.
(b) As you have learned in the text, the principle of linear superposition of wave displacement is basic to understanding distributions in diffraction and interference patterns. What is the justification of this principle?
Answer:
(a) When a low flying aircraft passes overhead, the metallic body of the aircraft reflects the TV signal. A slight shaking of the picture on the TV screen takes place due to the interference of the reflected signal from the aircraft and the direct signal received by the antenna.
(b) The linear combination of wave equations is also a wave equation. This is the very basis of the superposition principle.

Question 21.
In deriving the single slit diffraction pattern, it was stated that the intensity is zero at angle of nλ/α. Justify this by suitably dividing the slit to bring out the cancellation.
Answer:
Let us suppose that we have n slits each of width
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 15
Therefore, each of the n slits of width d’ each sends zero intensity in the direction 9. As a result, the net resultant of intensity due to n such slits is zero.

We hope the We hope the NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics, help you. If you have any query regarding NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments are part of NCERT Solutions for Class 12 Physics. Here we have given. NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments

Board CBSE
Textbook NCERT
Class Class 12
Subject Physics
Chapter Chapter 9
Chapter Name Ray Optics and Optical Instruments
Number of Questions Solved 37
Category NCERT Solutions

Question 1.
A small candle 2.5 cm in size is placed 27 cm in front of a concave mirror of a radius of curvature of 36 cm. At what distance from the mirror should a screen be placed in order to receive a sharp image? Describe the nature and size of the image. If the candle is moved closer to the mirror, how would the screen have to be moved?
Answer:
Here, h = 2.5 cm, u = – 27 cm, R = – 36 cm.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 1
Nature of image : Real, inverted and magnified. When the position of the object (i.e. candle) is moved closer to the concave mirror, the distance of the image moves away from the screen till the distance of the candle from the concave mirror is less than 18 cm. Hence, the screen has to be moved away from the concave mirror. When the distance of the candle is less than 18 cm from the concave mirror, a virtual and magnified image of the candle is formed behind the mirror. This image is not obtained on the screen.

Question 2.
A 4.5 cm needle is placed 12 cm away from a convex mirror of focal length 15 cm. Give the location of the image and magnification. Describe what happens as the needle is moved farther from the mirror.
Answer:
Here, h1 = 4.5 cm, μ = – 12 cm, f= 15 cm
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 2
Thus, the image is virtual, erect and diminished. As we move the needle away from the mirror, the image goes on decreasing in size and moves towards the principal focus on the other side.

Question 3.
A tank is filled with water to a height of 12.5 cm. The apparent depth of the needle lying at the bottom of the tank is measured by a microscope to be 9.4 cm. What is the refractive index of water ? If water is replaced by a liquid of refractive index 1.63 up to the same height, by what distance would the microscope have to be moved to focus on the needle again ? (C.B.S.E. 2009 )
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 3

Question 4.
The following figures (a) and (b) show refraction of an incident ray in air at 60° with the normal to glass-air and water-air interface, respectively. Predict the angle of refraction of an incident ray in water at 45° with the normal to a water-glass interface [Fig. (c)]
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 4
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 5
Question 5.
A small bulb is placed at the bottom of a tank containing water to a depth of 80 cm. What is the area of the surface of water through which light from the bulb can emerge out ? Refractive index of water is 1.33 (consider the bulb to be a point source).
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 6
The light rays from the bulb B, which fall on the surface of water at an angle equal to critical angle (θC), grazes on the surface of water and the rays of light which fall on the surface of water at an angle greater than θC are totally internally reflected back into the water. The rays of light images emerges out of water through a circular patch of radius r.

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and OptNCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 7ical Instruments 7

Question 6.
A prism is made of glass of unknown refractive index. A parallel beam of light is incident on a face of the prism. By rotating the prism, the angle of minimum deviation is measured to be 40°. What is the refractive index of the material of the prism ? If the prism is placed in water (refractive index 1.33), predict the new angle of minimum deviation of a parallel beam of light. The refracting angle of the prism is 60°.
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 8
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 9

Question 7.
Double-convex lenses are to be manufactured from a glass of refractive index 1.55, with both faces of the same radius of curvature. What is the radius of curvature required if the focal length is to be 20 cm ?
Answer:
Here, n = 1.55, R1 = R and R2 = – R, f= 20 cm Using lens maker formula, we get
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 10
Question 8.
A beam of light converges to a point P. A lens is placed in the path of the convergent beam 12 cm from P. At what point does the beam converge if the lens is (a) a convex lens of focal length 20 cm, (b) a concave lens of focal length 16 cm?
Answer:
(a) When a convex lens is placed in the path of light converging at P, the beam converges at Pt. Thus, point P acts as virtual object for the convex lens.
Now, u = 12 cm, f= 20 cm.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 11
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 12

Question 9.
An object of size 3.0 cm is placed 14 cm in front of a concave lens of focal length 21 cm. Describe the image produced by the lens. What happens if the object is moved farther from the lens?
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 13
Thus, the image is virtual, erect, diminished and is formed on the same side of the lens at a distance of 8.4 cm from the lens. If the object is moved away from the lens, the image moves towards the principal focus and goes on decreasing in size.

Question 10.
What is the focal length of a convex lens of focal length 30 cm in contact with a concave lens of focal length 20 cm? Is the system a converging or a diverging lens? Ignore thickness of the lenses.
Answer:
Here, f1 = 30 cm and f2 = -20 cm
For the combination of two thin lenses, the focal length of the combination is given by
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 14
Since the focal length of the system of lens is negative, therefore, the combination behaves as a diverging lens.

Question 11.
A compound microscope consists of an objective lens of focal length 2-0 cm and an eye-piece of focal length 6.25 cm separated by a distance of 15 cm. How far from the objective should an object be placed in order to obtain the final image at (a) the least distance of distinct   vision (25 cm), (b) infinity ? What is the magnifying power of the microscope in each case? (C.B.S.E. 2008)
Answer:
Here, fn =2.0 cm, f = 6.25 cm,
Distance between object lens and eye piece = 15 cm (a) For the formation of image at the least distance of distinct vision,
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 15
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 16

Question 12.
A person with a normal near point (25 cm) using a compound microscope with objective of focal length 8.0 mm and an eye-piece of focal length 2.5 cm can bring an object placed 9.0 mm from the objective in sharp focus. What is the separation between the two lenses ? How much is the magnifying power of the microscope?
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 17
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 18

Question 13.
A small telescope has an objective lens of focal length 144 cm and an eye-piece of focal length 6.0 cm. What is the magnifying power of the telescope? What is the separation between the objective and the eye-piece?
Answer:
Here, focal length of objective lens, f0 = 144 cm Focal

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 19

Question 14.
(a) A giant refracting telescope at an observatory has an objective lens of focal length 15m. If an eye-piece of focal length 1.0 cm is used, what is the angular magnification of the telescope ?
(b) If this telescope is used to view the moon, what is the diameter of the image of the moon formed by the objective lens ? The diameter of the moon is 3.48 x 106m and the radius of the lunar orbit is 3.8 x 108m. (C.B.S.E. 2008, 2011)
Answer:

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 20

Question 15.
Use the mirror equation to deduce that
(a) an object placed between f and 2f of a concave mirror produces a real image beyond 2f.
(b) a convex mirror always produces a virtual image independent of the location of the object.
(c) the virtual image produced by a convex mirror is always diminished in size and is located between the focus and the pole.
(d) an object placed between the pole and focus of a concave mirror produces a virtual and enlarged image. (C.B.S.E. 2011)
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 21
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 22
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 23

Question 16.
A small pin fixed on the table top is viewed from above from a distance of 50 cm. By what distance would the pin appear to be raised if it is viewed from the same point through a 15 cm thick glass slab held parallel to the table?
Refractive index of glass = 1.5. Does the answer depend upon the location of the slab?
Answer:
Here, t = 15 cm, n = 1.5
The lateral displacement

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 24
For small angles of incidence, the answer does not depend upon the location of the slab.

Question 17.
(a) Following figure shows a cross-section of a ‘light pipe’ made of glass fibre of refractive index 1.68. The outer covering of the pipe is made of material of refractive index 1.44. What is the range of the angles of incident rays with the axes of the pipe for which the total internal reflection inside the pipe take place as shown in the figure ?
(b) What is the answer if there is no outer covering of pipe ?
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 25
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 26
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 27
Therefore all incident rays in the range 0 to 90°suffer total internal refletion.

Question 18.

Answer the following questions:
(a) You have learned that plane and convex mirrors produce virtual images of objects. Can they produce real images under some circumstances ? Explain.
(b) A virtual image, we always say, cannot be caught on a screen. Yet when we ‘see’ a virtual image, we are obviously bringing it on to the ‘screen’ (i.e., the retina) of our eye. Is there a contradiction?
(c) A diver under water, looks obliquely at a fisherman standing on the bank of a lake, would the fisherman look taller or shorter to the diver than what he actually is ?
(d) Does the apparent depth of a tank of water change if viewed obliquely ? If so, does the apparent depth increase or decreases
(e) The refractive index of diamond is much greater than that of ordinary glass. Is this fact of some use to a diamond cutter ?
Answer:
(a) Yes. They can produce real images if the object is a virtual object as shown in figure.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 28
(b) here is no contradiction in this case. The virtual image of the object acts as an object for the convex lens of our eye and the lens of our eye make a real image of this object on the ratina.
(c) Let AB be the fisherman standing on the bank of the lake. The rays of light from the head of the fisherman bends towards the normal on refraction at the interface separating water and air. The refracted rays appear to come from point B’ instead of point B for the fish. Thus, for a diver the height of the fisherman is AB’ which is greater than his actual height AB.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 29
(d) The apparent depth of a pond of water decreases when viewed obliquely. This is due to the refraction of light from the surface of water.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 30
Question 19.
The image of a small electric bulb fixed on the wall of a room is to be obtained on the opposite wall 3 m away by means of a large convex lens. What is the maximum possible focal length of the lens required for the purpose ?
Answer:
The minimum distance between a real object and its real image formed by a convex lens of focal length/is given by L = 4f

Question 20.
A screen is placed 90 cm from an object. The image of the object on the screen is formed by a convex lens at two different locations separated by 20 cm. Determine the focal length of the lens.
Answer:
Let O be the position of object and I is the position of image when lens is at L1 and then at L2
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 31

Question 21.
(a) Determine the effective focal length of the combination of the two lenses in the question 910 if they are placed 8.0 cm apart with their principal axes coincident. Does the answer depend on which side a beam of parallel light is incident ? Is the notion of effective focal length of this system useful at all ?
(b) An object 1.5 cm in size is placed on the side of the convex lens in the above arrangements. The distance between the object and the convex lens is 40 cm. Determine the magnification produced by the two-lens system, and the size of the image.
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 32

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 33

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 34

Question 22.
At what angle should a ray of light be incident on the face of a prism of refracting angle 60° so that it just suffers total internal reflection at the other face ? The refractive index of the material of the prism is 1.524.
Answer:
Let the ray of light be incident on the face AB at angle i so that it is totally internally reflected at face AC.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 35

Question 23.
You are given prism made of crown glass and flint glass with a wide variety of angles. Suggest a combination of prisms which will (a) deviate a pencil of white light without much dispersion (b) disperse (and displace) a pencil of white light without much deviation.
Answer:
(a) 
Angular dispersion produced by two prisms i.e. crown glass and flint glass should be zero in this case
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 36
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 37
In the combination of prisms, flint glass prism of greater angle may be tried but in any case still this angle will be smaller than the angle of the crown glass prism in opposite order as shown in figure.

Question 24.
For a normal eye, the far point is at infinity and the near point of distinct vision is about 2.5 cm in front of the eye. The cornea of the eye provides a converging power of about 40 dioptres, and the least converging power of the eye lens behind the cornea is about 20 dioptres. From this rough data estimate the range of accommodation {i.e., the range of converging power of the eye-lens) of a normal eye.
Answer:
When the object is placed at infinity, the eye makes use of the least converging power, Therefore, total converging power of cornea and the eye lens = 40 + 20 = 60 dioptre.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 38

Question 25.

Does short-sightedness (myopia) or long-sightedness (hypermetropia) imply necessarily that the eye has partially lost its ability of accommodation ? If not, what might cause these defects of vision ?
Answer:
No. Myopia may arise due to the elongation of the eye ball and hypermetropia may arise due to the decrease in the size of the eye ball even when the eye has the normal ability of accommodation. There is another defect in the eye called presbyopia similar to hypermetropia. However, the causes of presbyopia and hypermetropia are different. Presbyopia arises in elderly persons and is corrected by using a bi-focal lens.

Question 26.
A myopic person has been using spectacles of power – 1.0 dioptres for distant vision. During old age he also needs to use separate reading glass of power +2 dioptres. Explain what may have happened.
Answer:
For -1.0 dioptre, the far point for eyes is 1 m i.e. 100 cm. The near point is 25 cm. The objects lying at infinity are brought at 100 cm from his eyes using the concave lens and the objects lying in between 25 cm and 100 cm are brought to focus using the ability of accommodation of the eye lens. In the old age, this ability of accommodation is reduced and the near point reaches 50 cm from his eyes.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 39

Question 27.

A person looking at a mesh of crossed wires is able to see the vertical wires more distinctly than the horizontal wires. What is this defect due to ? How is such a defect of vision corrected ?
Answer:
This is due to the defect of lenses called astigmatism. The defect arises because of the fact that curvature of the eye-lens and the cornea is not same in different planes. This defect is removed by using cylindrical lens with vertical axis.

Question 28.
A man with normal near point (25 cm) reads a book with small print using a magnifing glass: a thin convex lens of focal length 5 cm.
(a) What is the closest and the farthest distance at which he can read the book when viewing through the magnifying glass ?
(b) What is the maximum and minimum angular magnification (magnifying power) possible using the above simple microscope ?
Answer:
(a) To see the object at a closest distance, the image of object should be formed at the least distance of distinct vision.
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 40
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 41
Question 29.
A card sheet divided into squares each of size 1 mm2 is being viewed at a distance of 9 cm through a magnifying glass (a converging lens of focal length 10 cm) held close to eye.
(a) What is the magnification (image size/object size) produced by the lens ? How much is the area of each square in the virtual object ?
(b) What is the angular magnification (magnifying powers) of the lens ?
(c) Is the magnification in
(1) equal to magnifying power in
(2) ? Explain.
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 42
(c) Clearly magnification and power magnification are not equal to each other unless the image is located near the least distance of distinct vision, e. v = D.

Question 30.
(a) At what distance should the lens be held from the figure in the above exercise in order to view the squares distinctly with maximum possible magnifying power ?
(b) What is the magnification (image size/object size) in this case ?
(c) Is the magnification equal to magnifying power in this case ? Explain.
Answer:
(a) The magnifying power is maximum if the image is formed at the least distance of distinct point from the eye, i.e., if υ = -25 cm ; Also, f = 10 cm
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 43
=> the linear magnification and magnifying power is equal in this case.

Question 31.
What should be the distance between the object in the previous exercise and the magnifying glass if the virtual image of each square in the figure is to have an area 6.25 mm2? Would you be able to see the squares distinctly with your eyes very close to the magnifier?
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 44

Question 32.

Answer the following questions :
(а) 
The angle subtended at the eye by an object is equal to the angle subtended at the eye by the virutal image produced by a magnifying glass. In what sense then does a magnifying glass provide angular magnification?
(b) In viewing through a magnifying glass, one usually positions one’s eyes very close to the lens. Does angular magnification change if the eye is moved back?
(c) Magnifying power of a simple microscope is inversely proportional to the focal length of the lens. What then stops us from using a convex lens of smaller and smaller focal length and achieving greater and greater magnifying power?
(d) Why must both the objective and the eye-piece of a compound microscope have short focal lengths?
(e) When viewing through a compound microscope, our eyes should be positioned not on the eye-piece but a short distance away from it for best viewing. Why? How much should be that short distance between the eye and eyepiece?
Answer:
(a) When magnifying glass is not used, object to be seen clearly is to be placed at 25 cm. However, while using magnifying glass, object can be placed closer to eye than at 25 cm. The closer object has large angular size than the same object placed at 25 cm. It is in this sense that magnifying glass provides angular magnification.
(b) Yes. The angular magnification decreases slightly because angle subtended at eye is somewhat less than the angle subtended at the lens.
(c) The aberrations like spherical and chromatic aberrations start croping up if the convex lens of smaller and smaller focal length is made.
(d) Angular magnification of eye piece is given by (1+D/fe)  and angular magnification of objective is approximately given by υ/f0. Clearly for better magnification focal length of eye piece fe and focal length of objective fe should be small.
(e) If we position our eye very close to the eyepiece, the whole light will not fall on our eye and the field of view will decrease. So we place our eye a short distance away from the eye-piece to collect the large amount of light refracted through the eyepiece to increase the field of view.

Question 33.
An angular magnification (magnifying power) of 30 X is desired using an objective of focal length 1.25 cm and eye piece of focal length 5 cm. How will you set up the compound microscope ?
Answer:
For the image formed at the least distance of distinct vision, the magnifying power is given by
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 45
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 46

Question 34.

A small telescope has an objective lens of focal length 140 cm and an eye piece of focal length 5.0 cm. What is the magnifying power of the telescope for viewing distant objects when
(a) the telescope is in normal adjustment (i.e.,when the final image is formed at infinity) ?
(b) the final image is formed at the least distance of distinct vision (25 cm) ?
Answer:
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 47
Question 35.
For the telescope described in the last exercise, in 9.34
(a) what is the separation between the objective lens and the eye-piece ?
(b) If this telescope is used to view a 100 m tall tower 3 km away, what is the height of image of the tower formed by objective lens ?
(c) What is the height of final image of the tower if it is formed at 25 cm ?
Answer:
(a) Since the final image is formed at infinity, the distance between the object lens and the eye-piece is f0 + fe = 140 + 5 = 145 cm
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 48

Question 36.

A cassegrain telescope uses two mirrors as shown in figure. Such a telescope is built with mirrors 20 mm apart. If the radius of curvature of large mirror is 220 mm and the small mirror is 140 mm, where will be the final image of an object at infinity be ?
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 49
Answer:

NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 50

Question 37.
The adjoining figure shows an equiconvex lens (of refractive index 1.50) in contact with a liquid layer on top of a plane mirror. A small needle with its tip on the principal axis is moved along the axis until its inverted image is found at the position of the needle. The distance of the needle from the lens is measured to be 45.0 cm. The liquid is removed and the experiment is repeated. The new distance is measured to be 30.0 cm. What is the refractive index of liquid ?
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 51
Answer:
In the presence of the liquid, the distance of the needle from the lens is equal to the focal length f of the combination of the convex lens and the piano concave lens formed by the liquid below it i.e. f = 45 cm. Also n = 1.5
In the absence of the liquid, the distance of the needle and the lens is equal to the focal length of the convex lens only i.e. f = 30 cm
.’.  If f2 is the focal length of plane concave lens formed
NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments 52

We hope the NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments, help you. If you have any query regarding NCERT Solutions for Class 12 Physics Chapter 9 Ray Optics and Optical Instruments, drop a comment below and we will get back to you at the earliest.

NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields

NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields

NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields part of NCERT Solutions for Class 12 Physics. Here we have given. NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields

Board CBSE
Textbook NCERT
Class Class 12
Subject Physics
Chapter Chapter 1
Chapter Name Electric Charges and Fields
Number of Questions Solved 34
Category NCERT Solutions

Question 1.
What is the force between two small charged spheres having charges of 2 x 10-7 C and 3 x 10-7 C placed 30 cm apart in the air?
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 1

Question 2.
The electrostatic force on a small sphere of charge 0.4 μC due to another small sphere of charge -0.8 μC in air is 0.2 N.
(a) What is the distance between the two spheres?
(b) What is the force on the second sphere due to the first?
Answer:
(a) Force on charge 1 due to charge 2 is given by the relation
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 2

Question 3.
Check that the ratio ke2/G memp. is dimensionless. Lookup a Table of Physical Constants and determine the value of this ratio. What does the ratio signify?
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 3
Thus, the given ratio is a number and is dimensionless. This ratio signifies that electrostatic force between electron and proton is very-very large as compared to the gravitational force between them.

Question 4.
(a) Explain the meaning of the statement ‘electric charge of a body is quantised.’
(b) Why can one ignore quantisation of electric charge when dealing with macroscopic i.e., large-scale charges?
Answer:
(a) Charge occurs in nature as a discrete entity. One packet of charge (least quantity) is called quantum charge. It is represented by ‘e‘. Generally, charge of an electron is represented by ‘e’ and charge of a proton is represented by ‘+ e’. Therefore, the charge possessed by any charged body will be an integral multiple of ± e, ie., ne where n = 1, 2, 3,
∴ q = ± ne
The fact that electric charge collections are integral multiples of the fundamental electronic charge was proved experimentally by Millikan.

(b) While dealing with the large-scale electrical phenomenon, we ignore the quantization of charge because the magnitude of charge of proton and electron is so small. For continuous charge distribution, charge can be accounted in terms of charge density such as linear charge density λ etc. We need not go for individual charges.

Question 5.
When a glass rod is rubbed with a silk cloth, charges appear on both. A similar phenomenon is observed with many other pairs of bodies. Explain how this observation is consistent with the law of conservation of charge.
Answer:
Before rubbing, both the glass rod and the silk cloth are electrically neutral. In other words, the net charge on the glass rod and the silk cloth is zero. When the glass rod is rubbed with silk cloth, a few electrons from the glass rod get transferred to the silk cloth. As a result, the glass rod becomes positively charged and the silk cloth negatively charged. Since the magnitude of positive charge on the glass rod is the same as that of negative charge on the silk, the net charge on the system is zero. Thus the appearances of charge on the glass rod and the silk cloth is in accordance with the law of conservation of charges.

Question 6.
Four-point charges qA = 2 μC, qB = -5 μC, or qc = -2 μC and qD = -5 μC are located at the corners of a square ABCD of side 10 cm. What is the force on a charge of 1μC placed at the center of the Square?
Answer:
The symmetry of the figure clearly indicates that 1μC charge will experience equal and opposite forces due to equal charges of 2μC placed at A and C. Similarly, 1μC charge will experience equal and opposite forces due to -5 μC charges placed at D and B.
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 4
Thus, net force = zero.

Question 7.
(a) An electrostatic field line is a continuous curve.
That is, a field line cannot have sudden breaks. Why not?
(b) Explain why two field lines never cross each other at any point?
Answer:
(a) Electric lines of force exist throughout the region of an electric field. The electric field of a charge decreases gradually with increasing distance from it and becomes zero at infinity (i)e., electric field can’t vanish abruptly. So a line of force can’t have sudden breaks, it must be a continuous curve.

(b) If two lines of force intersect, then there would be two tangents and hence two directions of electric fields at the point of intersection, which is not possible.

Question 8.
Two-point charges qA = 3μC and qB = -3 μC are located 20 cm apart in vacuum.
(a) What is the electric field at the midpoint O of the line AB joining the two charges?
(b) If a negative test charge of magnitude 1.5 x 10-9 C is placed at this point, what is the force experienced by the test charge? (C.B.S.E. 2003)
Answer:
(a) Electric field at the midpoint of the separation between two equal and opposite charges is given by
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 5

NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 6
(b) Force experienced by test charge = q0E
= (1.5 x 10-9) (5.4 x 106)
= 8.1 x 10-3 N along BA

Question 9.
A system has two charges qA = 2.5 x 10-7 C and qB = -2.5 x 10-7 C located at points
A : (0,0, -15 cm) and B : (0, 0, + 15 cm), respectively. What are the total charge and electric dipole moments of the system?
Answer:
Clearly, the given points are lying on the z-axis.
Distance between charges, 21
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 7
= 15 + 15 = 30 cm = 0.3 m
Total charge = (2.5 x 10-7) – (2.5 x 10-7) = 0
Dipole moment
= q x 21 = 2.5 x 10-7 x 0.3
= 7.5 x 10-8 C m along negative z-axis.

Question 10.
An electric dipole with dipole moment 4 x 10-9 Cm is aligned at 30° with the direction of a uniform electric field of magnitude 5 x 104 NC-1. Calculate the magnitude of the torque acting on the dipole.
Answer:
Using τ = pE sin 0, we get
= (4 x 10-9) (5x 10-4 sin 30°)
= 2 x 10-4 x \(\frac { 1 }{ 2 } \) = 10-4 N m 2

Question 11.
A polythene piece rubbed with wool is found to have a negative charge of 3.2 x 10-C.
(a) (Estimate the number of electrons transferred (from which to which ?)
(b) Is there a transfer of mass from wool to polythene?
Answer:
(a) Using q = ne, we get
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 8
(b) Yes, but of negligible amount because mass of an electron is very-very small (mass transferred = me x n = 91 x 10-31 x 2 x 1012 = 1.82 x 10-18 kg).

Question 12.
(a) Two insulated charged copper spheres A and B have their centers separated by a distance of 50 cm. What is the mutual force of electrostatic repulsion if the charge on each is 6.5 x 107 C ? The radii of A and B are negligible compared to the distance of separation.
(b) What is the force of repulsion if each sphere is charged double the above amount, and the distance between them is halved?
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 9

Question 13.
Suppose the spheres A and B in Q 1.12 have identical sizes. A third sphere of the same size but uncharged is brought in contact with the first, then brought in contact with the second, and finally removed from both. What is the new force of repulsion between A and B?
Answer:
Charge on sphere A on contact with the third sphere (say C) having no charge is given by
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 10
When third sphere, how having charge 3.25 10-7 C is brought in contact with sphere B, the charge left on sphere B is given by,
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 11

NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 12

Question 14.
Figure shows tracks of three charged particles in a uniform electrostatic field. Give the signs of the three charges. Which particle has the highest charge to mass ratio?
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 13
Answer:
Unlike charges attract each other, therefore particle 1 and 2 are negatively charged whereas particle 3 has a positive charge. Particle 3 gets maximum deflection so it has the highest charge (e) to mass (m) ratio because deflection, y α e/m

Question 15.
Consider a uniform electric field \(\overrightarrow { E } \)
= 3 x 103 \(\hat { i } \)N/C.
(a) What is the flux of this field through a square of 10 cm on a side whose plane is parallel to the yz plane?
(b) What is the flux through the same square if the normal to its plane makes a 60° angle with the x-axis?
Answer:
(a) Electric flux through the square,
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 14

Question 16.
What is the net flux of the uniform electric field of Problem 1.15 through a cube of the side 20 cm oriented so that its faces are parallel to the co­ordinate planes?
Answer:
Zero, because the number of field lines entering the cube is equal to the number of field lines coming out of the cube.

Question 17.
Careful measurement of the electric field at the surface of a black box indicates that the net outward flux through the surface of the box is 8.0 x 103 Nm2/C.
Answer:
(a) What is the net charge inside the box?
(b) If the net outward flux through the surface of the box were zero, could you conclude that there were no charges inside the box? Why or why not?
Ans.
(a) Using φ = φ /ε0 we get q =φ ε0
= (8 x 103) (8.854 x 10-12)
= 70.8 x 10-9 C = 0.07 μC
(b) No, it cannot be said so because there may be an equal number of positive and negative elementary changes inside the box. It can only be said that the net charge inside the box is zero.

Question 18.
A point charge + 10 μC is a distance 5 cm directly above the center of a square of side 10 cm, as shown in the given figure. What is the magnitude of the electric flux through the square? [Hint. Think of the square as one fact of a cube with edge 10 cm.]
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 15
Answer:
The charge can be assumed to be placed as shown in the figure.
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 16

Question 19.
A point charge of 2.0 μC is at the center of a cubic Gaussian surface 9.0 cm on edge. What is the net electric flux through the surface?
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 17

Question 20.
A point charge causes an electric flux of -1.0 x 103 Nm2/C to pass through a spherical Gaussian surface of a 10.0 cm radius centered on the charge.
(a) If the radius of the Gaussian surface were doubled, how much flux would pass through the surface?
(b) What is the value of the point charge?
Answer:
(a) The electric flux depends only on the charge enclosed by the Gaussian surface and independent of the size of the Gaussian surface. The electric flux through new Gaussian surface remains same
i.e. -1 x 103 Nm2 C-1 because the charge enclosed remains same in this case also.
(b) Using φ = q/ε0, we get q = ε0 φ = (8.85 x 10-12) (-1 x 103)
i.e. q = -8.85 x 10-9 C.

Question 21.
a conducting sphere of radius 10 cm has an unknown charge. If the electric field 20 cm from the center of the sphere is 1.5 x 103 N/C and points radially inward, what is the net charge on the sphere?
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 18
Question 22.
A uniformly charged conducting sphere of 2.4 m diameter has a surface charge density of 80.4 μC /m2.
(a) Find the charge on the sphere.
(b) What is the total electric flux leaving the surface of the sphere? (B.S.E. 2009 C)
Answer:
(a) Charge on the sphere is given by
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 19

Question 23.
An infinite line charge produces a field of 9 X 104 N/C at a distance of 2 cm. Calculate the linear charge density
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 20

Question 24.
Two large, thin metal plates are parallel and close to each other. On their inner faces, the plates have surface charge densities of opposite signs and of magnitude 17.0 x 10-22 C/m2. What is E?
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 21
(a) in the outer region of the first plate,
(b) in the outer region of the second plate, and
(c) between the plates?
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 22

Question 25.
An oil drop of 12 excess electrons is held stationary under a constant electric field of 2.55 x 104 NC-1 in Millikan’s oil drop experiment. The density of the oil is 1.26 g cm-3. Estimate the radius of the drop, (g = 9.81 ms-2 ; e = 1.60 x 10-19 C.)
Answer:
Charge on the drop,
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 23

Question 26.
Which among the curves shown in the figure cannot possibly represent electrostatic field lines?
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 24
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 25
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 26
Answer:
(a) Incorrect, because the field lines should be normal to the surface of a conductor.
(b) Incorrect, because the field lines cannot start from a negative charge.
(c) Correct
(c) Incorrect, because electric field lines cannot intersect with each other.
(d) Incorrect, because electrostatic field lines cannot form a closed loop.

Question 27.
In a certain region of space, the electric field is along the z-direction throughout. The magnitude of the electric field is, however, not constant but increases uniformly along the positive z-direction, at the rate of 105 N C-1 per meter. What are the force and torque experienced by a system having a total dipole moment equal to 10-7 C m in the negative z-direction?
Answer:
Suppose the dipole is along the z-axis.
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 27
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 28
Question 28.
(a) A conductor A with a cavity as shown in figure (a) is given a charge Q. Show that the entire charge must appear on the outer surface of the conductor.
(b) Another conductor B with charge q is inserted into the cavity keeping B insulated from A. Show that the total charge on the outside surface of A is Q + q [Figure (b)].
(c) A sensitive instrument is to be shielded from the strong electrostatic fields in its environment. Suggest a possible way.
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 29
Answer:
Select a Gaussian surface lying wholly inside the conductor but very near to the surface of the conductor.
(a) There is no electric field inside the conductor so electric flux through Gaussian surface is zero or in other words, net charge inside the Gaussian surface is zero. Then it can be said that the charge lies outside the Gaussian surface e. on the outer surface of the conductor.
(b) Charge q inside the cavity will induce a charge -q on the inner side of the cavity and thus +q will appear on the outer surface. Thus total charge will be (q + Q).
(c) The instrument should be enclosed in a metallic shell so that the effect of the electrostatic field is cancelled out.

Question 29.
A hollow charged conductor has a tiny hole cut into its surface. Show that the electric field in the hole is (σ/2ε0) \(\hat { n } \), where \(\hat { n } \) is the unit vector in the outward normal direction, and a is the surface charge density near the hole.
Answer:
Let the tiny hole of the conductor be considered as filled up. The field inside the conductor is zero, whereas outside it is given by
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 30
This field is infact due to
(1) field (E1) due to plugged hole and
(2) field E2 due to rest of the charged conductor. Inside the conductor, these fields are equal but opposite, whereas outside they are exactly same. i.e.
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 31

Question 30.
Obtain the formula for the electric field due to a long thin wire of uniform linear charge density X without using Gauss’s law.
[Hint. Use Coulomb’s law directly and evaluate the necessary integral.]
Answer:
Consider a long thin wire of uniform linear charge density X placed along the X-axis. Let P be a point lying on the y-axis
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 42
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 33
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 34
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 35
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 36

Question 31.

It is now believed that protons and neutrons (which constitute nuclei of ordinary matter) are themselves build-out of more elementary units called quarks. A proton and a neutron consist of three quarks each. Two types of quarks, the so called ‘up’ quark (denoted by u) of charge + (2/3)e, and the ‘down’ quark (denoted by d) of charge
(-l/3)e, together with electrons build up ordinary matter. (Quarks of other types have also been found which give rise to different unusual varieties of matter.) Suggest a possible quark composition of a proton and neutron.)
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 37

Question 32.
(a) Consider an arbitrary electrostatic field configuration. A small test charge is placed at a null point (i.e., where E = 0) of the configuration. Show that the equilibrium of the test charge is necessarily unstable.
(b) Verify this result for the simple configuration of two charges of the same magnitude and sign placed a certain distance apart.
Answer:
(a) To prove the result, let us assume that the test charge placed at the null point is in stable equilibrium. If it is so, then on being displaced slightly away from the null point, the test charge should return to its position., It implies that if a closed surface is drawn around the test charge, there will be a net inward flux of the electric field through its surface. According to Gauss law, there cannot be any electric flux through its surface as it does not enclose any charge. Hence our assumption is wrong and the test

(b) For the configuration of the two charges of the same magnitude and sign, the null point is the midpoint of the line joining the two charges. If the test charge is displaced slightly from the null point along the line, it will return back due to the restoring force that comes into the day. But if the charge is displaced slightly from the null – point along normal to the line it will not return. This is because the resultant force due to the configuration of two charges will take it away from the null point. For the test charge to be in stable equilibrium restoring force must come into play, when it is displaced in any direction. Hence the test charge cannot be in stable equilibrium.

Question 33.
A particle of mass m and charge (-q) enters the region between the two charged plates initially moving along x-axis with speed σx, (like particle 1 in figure.) The length of plate is L and a uniform electric field E is maintained between the plates. Show that the vertical deflection of the particle at the far edge of the plate is qEL2/(2m υx2).
Compare this motion with motion of a projectile in gravitational field discussed in Section 4.10. of Class XI Textbook of Physics.
Answer:
Consider a uniform electric field \(\overrightarrow { E } \) set up between two oppositely charged parallel plates (Figure). Let a positively charged particle having charge +q and mass m enters the region of electric field E at O with velocity E along X-direction.
Step 1.
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 38
Force acting on the charge +q due to electric field E is given by
\(\overrightarrow { F } \) =Q \(\overrightarrow { E } \)
The direction of the force is along the direction of
\(\overrightarrow { E } \)and hence the charged particle is deflected accordingly.
Acceleration produced in the charged particle is given by

NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 39
Step 2.
The charged particle will accelerate in the direction of E . As soon as the particle leaves the region of electric field, it travels due to inertia of motion and hits the screen at point P. Let t be the time taken by the charged particle to traverse the region of electric field of length L. Let y be the distance travelled by the particle along y-direction (i.e. direction of electric field). Using a standard equation of motion,
S = ut + \(\frac { 1 }{ 2 } \) at2.
For horizontal motion. S = L, u = υx and a = 0.
(∴ no force acts on the particle along x-direction)
From equation (ii), we have
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 40
Equation (i) is the equation of a parabola.
Hence a charged particle moving in a uniform electric field follows a parabolic path.

Question 34.
Suppose that the particle in Q 1.33 is an electron projected with velocity
υx = 2.0 x 106 ms-1. If E between the plates separated by 0.5 cm is 9.1 x 102 N/C, where
will the electron strike the upper plate ? ( |e| = 1.6 x 10-19 C, me = 9.1 x 10-31 kg.)
Answer:
NCERT Solutions for Class 12 Physics Chapter 1 Electric Charges and Fields 41

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